Home > Publications database > Topologically Sensitive Surface Segregations of Au-Pd Alloys in Electrocatalytic Hydrogen Evolution |
Journal Article | PUBDB-2015-00861 |
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2014
Wiley-VCH
Weinheim
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Please use a persistent id in citations: doi:10.1002/celc.201300112
Abstract: Density functional calculations along with in situ X-ray absorption spectroscopy data show that AuPd alloys form unique potential-controlled surface structures during the hydrogen evolution. We find evidence for surface segregations preferring a gold surface if the surface is free of chemisorbed species, while hydrogen adsorption triggers palladium segregation into the surface.
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