guest ::
| Home > Publications database > Sol–gel processing and electrochemical characterization of monoclinic $Li_{3}FeF_{6}$ |
| Home > Publications database > Sol–gel processing and electrochemical characterization of monoclinic $Li_{3}FeF_{6}$ |
| Journal Article | DESY-2014-02861 |
; ; ; ; ; ;
2014
Springer Science + Business Media B.V
Dordrecht [u.a.]
This record in other databases: 
Please use a persistent id in citations: doi:10.1007/s10971-014-3329-1
Abstract: To find new cathode materials for future applications in lithium-ion batteries, lithium transition metal fluorides represent an interesting class of materials. In principle the Li intercalation voltage can be increased by replacing oxygen in the cathode host structure with the more electronegative fluorine. A facile pyrolytic sol–gel process with trifluoroacetic acid as fluorine source was established to synthesize monoclinic Li3FeF6 using nontoxic chemicals. The acicular Li3FeF6 powder was characterized with X-ray diffraction and a detailed structure model was calculated by Rietveld analysis. For the preparationof cathode films to cycle versus lithium monoclinic Li3FeF6 was ball milled with carbon and binder down to nanoscale. After 100 cycles galvanostatic cycling (C/20) 47 % fully reversible capacity of the initial capacity (129 mAh/g) could be retained. To the best of our knowledge the results presented in this work include the first rate performance test for monoclinic Li3FeF6 up to 1 C maintaining a capacity of 71 mAh/g. The redox reaction involving Fe3?/Fe2? during Li insertion/extraction was confirmed by post-mortem XPS and cyclic voltammetry.
; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection ; Zoological Record
|
The record appears in these collections: |
PDF
Fulltext