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@ARTICLE{ChauSoederstroem:641757,
      author       = {Chau Soederstroem, Johan and Cornetta, Lucas M. and Ekholm,
                      Victor and Carravetta, Vincenzo and Brito, Arnaldo Naves de
                      and Marinho, Ricardo and Agaker, Marcus and Tokushima,
                      Takashi and Såthe, Conny and Ghosh, Anirudha and Bloss,
                      Dana and Hans, Andreas and Trinter, Florian and Ismail, Iyas
                      and Vasconcelos, Debora and Pinheiro, Joel and Chang,
                      Yi-Ping and Harder, Manuel and Yin, Zhong and Nordgren,
                      Joseph and Oehrwall, Gunnar and Ågren, Hans and Rubensson,
                      Jan-Erik and Bjoerneholm, Olle},
      title        = {{N}on-local {X}-ray intermolecular radiative decay probes
                      solvation shell of ions in water},
      journal      = {Nature Communications},
      volume       = {16},
      number       = {1},
      issn         = {2041-1723},
      address      = {[London]},
      publisher    = {Springer Nature},
      reportid     = {PUBDB-2025-05168},
      pages        = {10046},
      year         = {2025},
      note         = {Open Access},
      abstract     = {Aqueous solutions are crucial in chemistry, biology,
                      environmental science, and technology. The chemistry of
                      solutes is influenced by the surrounding solvation shell of
                      water molecules, which have different chemical properties
                      than bulk water due to their different electronic and
                      geometric structure. It is experimentally challenging to
                      selectively investigate this property-determining electronic
                      and geometric structure. Here, we report experimental
                      results on the non-local X-ray emission process
                      Intermolecular Radiative Decay, for the prototypical ions
                      Na+ and Mg2+ in water. We show that, in Intermolecular
                      Radiative Decay, an electron from the solvation shell fills
                      a core hole in the solute, and the released energy is
                      emitted as an X-ray photon. We interpret the underlying
                      mechanism using theoretical calculations, and show how
                      Intermolecular Radiative Decay will allow us to meet the
                      challenge of selectively probing the solvation shell from
                      within.},
      cin          = {DOOR ; HAS-User},
      ddc          = {500},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20251508
                      EC (I-20251508-EC) / 05K22RK1 - Verbundprojekt 05K2022 -
                      TRANSALP: Zeit- $\&$ winkelaufgelöste Spektroskopie an
                      Proben in der flüssigen Phase. Teilprojekt 2: Aufbau Liquid
                      Jet und KI-basierte Datenanalyse. (BMBF-05K22RK1) / DFG
                      project G:(GEPRIS)509471550 - Dynamik
                      photoionisations-induzierter Prozesse in laser-präparierten
                      Molekülen in der Gasphase und der wässrigen Phase
                      (509471550) / SWEDEN-DESY - SWEDEN-DESY Collaboration
                      $(2020_Join2-SWEDEN-DESY)$},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20251508-EC /
                      G:(DE-Ds200)BMBF-05K22RK1 / G:(GEPRIS)509471550 /
                      $G:(DE-HGF)2020_Join2-SWEDEN-DESY$},
      experiment   = {EXP:(DE-H253)P-P04-20150101},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1038/s41467-025-65581-7},
      url          = {https://bib-pubdb1.desy.de/record/641757},
}