000641757 001__ 641757
000641757 005__ 20251202213758.0
000641757 0247_ $$2doi$$a10.1038/s41467-025-65581-7
000641757 0247_ $$2datacite_doi$$a10.3204/PUBDB-2025-05168
000641757 037__ $$aPUBDB-2025-05168
000641757 041__ $$aEnglish
000641757 082__ $$a500
000641757 1001_ $$0P:(DE-H253)PIP1086781$$aChau Soederstroem, Johan$$b0$$eCorresponding author
000641757 245__ $$aNon-local X-ray intermolecular radiative decay probes solvation shell of ions in water
000641757 260__ $$a[London]$$bSpringer Nature$$c2025
000641757 3367_ $$2DRIVER$$aarticle
000641757 3367_ $$2DataCite$$aOutput Types/Journal article
000641757 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1764683546_1725264
000641757 3367_ $$2BibTeX$$aARTICLE
000641757 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000641757 3367_ $$00$$2EndNote$$aJournal Article
000641757 500__ $$aOpen Access
000641757 520__ $$aAqueous solutions are crucial in chemistry, biology, environmental science, and technology. The chemistry of solutes is influenced by the surrounding solvation shell of water molecules, which have different chemical properties than bulk water due to their different electronic and geometric structure. It is experimentally challenging to selectively investigate this property-determining electronic and geometric structure. Here, we report experimental results on the non-local X-ray emission process Intermolecular Radiative Decay, for the prototypical ions Na+ and Mg2+ in water. We show that, in Intermolecular Radiative Decay, an electron from the solvation shell fills a core hole in the solute, and the released energy is emitted as an X-ray photon. We interpret the underlying mechanism using theoretical calculations, and show how Intermolecular Radiative Decay will allow us to meet the challenge of selectively probing the solvation shell from within.
000641757 536__ $$0G:(DE-HGF)POF4-6G3$$a6G3 - PETRA III (DESY) (POF4-6G3)$$cPOF4-6G3$$fPOF IV$$x0
000641757 536__ $$0G:(DE-H253)I-20251508-EC$$aFS-Proposal: I-20251508 EC (I-20251508-EC)$$cI-20251508-EC$$x1
000641757 536__ $$0G:(DE-Ds200)BMBF-05K22RK1$$a05K22RK1 - Verbundprojekt 05K2022 - TRANSALP: Zeit- & winkelaufgelöste Spektroskopie an Proben in der flüssigen Phase. Teilprojekt 2: Aufbau Liquid Jet und KI-basierte Datenanalyse. (BMBF-05K22RK1)$$cBMBF-05K22RK1$$f05K22RK1$$x2
000641757 536__ $$0G:(GEPRIS)509471550$$aDFG project G:(GEPRIS)509471550 - Dynamik photoionisations-induzierter Prozesse in laser-präparierten Molekülen in der Gasphase und der wässrigen Phase (509471550)$$c509471550$$x3
000641757 536__ $$0G:(DE-HGF)2020_Join2-SWEDEN-DESY$$aSWEDEN-DESY - SWEDEN-DESY Collaboration (2020_Join2-SWEDEN-DESY)$$c2020_Join2-SWEDEN-DESY$$x4
000641757 588__ $$aDataset connected to CrossRef, Journals: bib-pubdb1.desy.de
000641757 693__ $$0EXP:(DE-H253)P-P04-20150101$$1EXP:(DE-H253)PETRAIII-20150101$$6EXP:(DE-H253)P-P04-20150101$$aPETRA III$$fPETRA Beamline P04$$x0
000641757 7001_ $$0P:(DE-HGF)0$$aCornetta, Lucas M.$$b1
000641757 7001_ $$0P:(DE-HGF)0$$aEkholm, Victor$$b2
000641757 7001_ $$0P:(DE-HGF)0$$aCarravetta, Vincenzo$$b3
000641757 7001_ $$0P:(DE-HGF)0$$aBrito, Arnaldo Naves de$$b4
000641757 7001_ $$0P:(DE-H253)PIP1010378$$aMarinho, Ricardo$$b5
000641757 7001_ $$0P:(DE-H253)PIP1018076$$aAgaker, Marcus$$b6
000641757 7001_ $$0P:(DE-HGF)0$$aTokushima, Takashi$$b7
000641757 7001_ $$0P:(DE-H253)PIP1086777$$aSåthe, Conny$$b8
000641757 7001_ $$0P:(DE-H253)PIP1094235$$aGhosh, Anirudha$$b9
000641757 7001_ $$0P:(DE-H253)PIP1025978$$aBloss, Dana$$b10
000641757 7001_ $$0P:(DE-H253)PIP1017360$$aHans, Andreas$$b11
000641757 7001_ $$0P:(DE-H253)PIP1017364$$aTrinter, Florian$$b12
000641757 7001_ $$0P:(DE-H253)PIP1027854$$aIsmail, Iyas$$b13
000641757 7001_ $$0P:(DE-H253)PIP1100582$$aVasconcelos, Debora$$b14
000641757 7001_ $$0P:(DE-H253)PIP1100585$$aPinheiro, Joel$$b15
000641757 7001_ $$0P:(DE-HGF)0$$aChang, Yi-Ping$$b16
000641757 7001_ $$0P:(DE-H253)PIP1013447$$aHarder, Manuel$$b17
000641757 7001_ $$0P:(DE-HGF)0$$aYin, Zhong$$b18
000641757 7001_ $$0P:(DE-H253)PIP1018086$$aNordgren, Joseph$$b19
000641757 7001_ $$0P:(DE-H253)PIP1025903$$aOehrwall, Gunnar$$b20
000641757 7001_ $$0P:(DE-H253)PIP1099688$$aÅgren, Hans$$b21
000641757 7001_ $$0P:(DE-H253)PIP1010960$$aRubensson, Jan-Erik$$b22
000641757 7001_ $$0P:(DE-H253)PIP1083875$$aBjoerneholm, Olle$$b23$$eCorresponding author
000641757 773__ $$0PERI:(DE-600)2553671-0$$a10.1038/s41467-025-65581-7$$gVol. 16, no. 1, p. 10046$$n1$$p10046$$tNature Communications$$v16$$x2041-1723$$y2025
000641757 8564_ $$uhttps://www.nature.com/articles/s41467-025-65581-7
000641757 8564_ $$uhttps://bib-pubdb1.desy.de/record/641757/files/Soederstroem_NatCommun_2025.pdf$$yOpenAccess
000641757 8564_ $$uhttps://bib-pubdb1.desy.de/record/641757/files/Soederstroem_NatCommun_2025.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000641757 909CO $$ooai:bib-pubdb1.desy.de:641757$$popenaire$$popen_access$$pVDB$$pdriver$$pdnbdelivery
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1086781$$aExternal Institute$$b0$$kExtern
000641757 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1086781$$aEuropean XFEL$$b0$$kXFEL.EU
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1010378$$aExternal Institute$$b5$$kExtern
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1018076$$aExternal Institute$$b6$$kExtern
000641757 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1086777$$aEuropean XFEL$$b8$$kXFEL.EU
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1086777$$aExternal Institute$$b8$$kExtern
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1094235$$aExternal Institute$$b9$$kExtern
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1025978$$aExternal Institute$$b10$$kExtern
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1017360$$aExternal Institute$$b11$$kExtern
000641757 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1017364$$aEuropean XFEL$$b12$$kXFEL.EU
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1017364$$aExternal Institute$$b12$$kExtern
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1027854$$aExternal Institute$$b13$$kExtern
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1100582$$aExternal Institute$$b14$$kExtern
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1100585$$aExternal Institute$$b15$$kExtern
000641757 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1013447$$aEuropean XFEL$$b17$$kXFEL.EU
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1018086$$aExternal Institute$$b19$$kExtern
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1025903$$aExternal Institute$$b20$$kExtern
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1099688$$aExternal Institute$$b21$$kExtern
000641757 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1099688$$aEuropean XFEL$$b21$$kXFEL.EU
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1010960$$aExternal Institute$$b22$$kExtern
000641757 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1083875$$aExternal Institute$$b23$$kExtern
000641757 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1083875$$aEuropean XFEL$$b23$$kXFEL.EU
000641757 9131_ $$0G:(DE-HGF)POF4-6G3$$1G:(DE-HGF)POF4-6G0$$2G:(DE-HGF)POF4-600$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Materie$$lGroßgeräte: Materie$$vPETRA III (DESY)$$x0
000641757 9141_ $$y2025
000641757 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2025-01-02
000641757 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2025-01-02
000641757 915__ $$0StatID:(DE-HGF)1050$$2StatID$$aDBCoverage$$bBIOSIS Previews$$d2025-01-02
000641757 915__ $$0StatID:(DE-HGF)1190$$2StatID$$aDBCoverage$$bBiological Abstracts$$d2025-01-02
000641757 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000641757 915__ $$0StatID:(DE-HGF)1040$$2StatID$$aDBCoverage$$bZoological Record$$d2025-01-02
000641757 915__ $$0StatID:(DE-HGF)9915$$2StatID$$aIF >= 15$$bNAT COMMUN : 2022$$d2025-01-02
000641757 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bNAT COMMUN : 2022$$d2025-01-02
000641757 915__ $$0StatID:(DE-HGF)0501$$2StatID$$aDBCoverage$$bDOAJ Seal$$d2024-01-30T07:48:07Z
000641757 915__ $$0StatID:(DE-HGF)0500$$2StatID$$aDBCoverage$$bDOAJ$$d2024-01-30T07:48:07Z
000641757 915__ $$0StatID:(DE-HGF)1030$$2StatID$$aDBCoverage$$bCurrent Contents - Life Sciences$$d2025-01-02
000641757 915__ $$0StatID:(DE-HGF)0700$$2StatID$$aFees$$d2025-01-02
000641757 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2025-01-02
000641757 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000641757 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2025-01-02
000641757 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bDOAJ : Peer review$$d2024-01-30T07:48:07Z
000641757 915__ $$0StatID:(DE-HGF)0561$$2StatID$$aArticle Processing Charges$$d2025-01-02
000641757 915__ $$0StatID:(DE-HGF)1060$$2StatID$$aDBCoverage$$bCurrent Contents - Agriculture, Biology and Environmental Sciences$$d2025-01-02
000641757 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2025-01-02
000641757 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2025-01-02
000641757 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2025-01-02
000641757 9201_ $$0I:(DE-H253)HAS-User-20120731$$kDOOR ; HAS-User$$lDOOR-User$$x0
000641757 980__ $$ajournal
000641757 980__ $$aVDB
000641757 980__ $$aUNRESTRICTED
000641757 980__ $$aI:(DE-H253)HAS-User-20120731
000641757 9801_ $$aFullTexts