guest ::
| Home > Publications database > Spatially Resolved In Situ X-ray Absorption Spectroscopy Studies of ZnS Nanoparticle Synthesis at the Water–Toluene Interface > print |
| Home > Publications database > Spatially Resolved In Situ X-ray Absorption Spectroscopy Studies of ZnS Nanoparticle Synthesis at the Water–Toluene Interface > print |
| 001 | 636202 | ||
| 005 | 20250817054533.0 | ||
| 024 | 7 | _ | |a 10.1021/acsnano.5c02875 |2 doi |
| 024 | 7 | _ | |a 1936-0851 |2 ISSN |
| 024 | 7 | _ | |a 1936-086X |2 ISSN |
| 024 | 7 | _ | |a 10.3204/PUBDB-2025-03627 |2 datacite_doi |
| 024 | 7 | _ | |a altmetric:179111519 |2 altmetric |
| 024 | 7 | _ | |a pmid:40627349 |2 pmid |
| 037 | _ | _ | |a PUBDB-2025-03627 |
| 041 | _ | _ | |a English |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Klemeyer, Lars |0 P:(DE-H253)PIP1083268 |b 0 |u desy |
| 245 | _ | _ | |a Spatially Resolved In Situ X-ray Absorption Spectroscopy Studies of ZnS Nanoparticle Synthesis at the Water–Toluene Interface |
| 260 | _ | _ | |a Washington, DC |c 2025 |b Soc. |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1755249957_3067124 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a Two-phase synthesis is a well-established approach for achieving precise control of the nanoparticle properties. However, studying and understanding chemical transformations in such a spatially heterogeneous system is challenging. In this work, we introduce a two-phase synthesis route for ZnS nanoparticles (ZnS NPs) at the water–toluene interface. By employing spatially resolved in situ high-energy resolution fluorescence-detected X-ray absorption spectroscopy (HERFD-XAS) combined with density functional theory (DFT) calculations, we track the diffusion of Zn$^{2+}$ species at the interface, identify key reaction intermediates, and monitor the nucleation and growth of ZnS NPs within the toluene phase. We propose the formation of a [Zn(H$_2$O)$_6$]$^{2+}$ complex upon dissolving Zn(Ac)$_2$ in water and the diffusion of Zn$^{2+}$ ions from water to toluene driven by the formation of an octahedral [Zn(OA)$_6$]$^{2+}$ complex (OA = oleylamine). Furthermore, by complementing HERFD-XAS with total X-ray scattering analysis, we show the formation of an intermediate tetrahedral [Zn(SR)4]$^{2+}$ complex at 60 °C and its successive transformation to noncrystalline ZnS nuclei at 80 °C and crystalline ZnS NPs starting at 100 °C. Thus, we demonstrate how in situ X-ray spectroscopy can elucidate the coordination and diffusion of Zn$^{2+}$ ions, and, in combination with X-ray scattering studies, identify the emergence of atomic and electronic structures during the two-phase synthesis of ZnS nanoparticles. |
| 536 | _ | _ | |a 632 - Materials – Quantum, Complex and Functional Materials (POF4-632) |0 G:(DE-HGF)POF4-632 |c POF4-632 |f POF IV |x 0 |
| 536 | _ | _ | |a 6G3 - PETRA III (DESY) (POF4-6G3) |0 G:(DE-HGF)POF4-6G3 |c POF4-6G3 |f POF IV |x 1 |
| 536 | _ | _ | |a LINCHPIN - A platform to LINk between CHemistry and PhysIcs of colloidal Nanomaterials (818941) |0 G:(EU-Grant)818941 |c 818941 |f ERC-2018-COG |x 2 |
| 536 | _ | _ | |a AIM, DFG project G:(GEPRIS)390715994 - EXC 2056: CUI: Advanced Imaging of Matter (390715994) |0 G:(GEPRIS)390715994 |c 390715994 |x 3 |
| 536 | _ | _ | |a GRK 2536 - GRK 2536: Hybridstrukturen auf der Nanometerskala: Chemische Konzepte zur Herstellung heterogener Nanostrukturen mit anisotropen Materialeigenschaften (NANOHYBRID) (408076438) |0 G:(GEPRIS)408076438 |c 408076438 |x 4 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: bib-pubdb1.desy.de |
| 693 | _ | _ | |a PETRA III |f PETRA Beamline P21.1 |1 EXP:(DE-H253)PETRAIII-20150101 |0 EXP:(DE-H253)P-P21.1-20150101 |6 EXP:(DE-H253)P-P21.1-20150101 |x 0 |
| 700 | 1 | _ | |a Caddeo, Francesco |0 P:(DE-H253)PIP1092080 |b 1 |
| 700 | 1 | _ | |a Gröne, Tjark L. R. |0 P:(DE-H253)PIP1098796 |b 2 |
| 700 | 1 | _ | |a Harouna-Mayer, Sani Y. |0 P:(DE-H253)PIP1083208 |b 3 |
| 700 | 1 | _ | |a Jessen, Brian |0 P:(DE-H253)PIP1090769 |b 4 |
| 700 | 1 | _ | |a Zito, Cecilia A. |0 P:(DE-H253)PIP1085597 |b 5 |
| 700 | 1 | _ | |a Kopula Kesavan, Jagadesh |0 P:(DE-H253)PIP1085745 |b 6 |
| 700 | 1 | _ | |a Dippel, Ann-Christin |0 P:(DE-H253)PIP1010723 |b 7 |u desy |
| 700 | 1 | _ | |a Igoa Saldana, Fernando |0 P:(DE-H253)PIP1100821 |b 8 |u desy |
| 700 | 1 | _ | |a Mathon, Olivier |0 P:(DE-HGF)0 |b 9 |
| 700 | 1 | _ | |a Glatzel, Pieter |0 0000-0001-6532-8144 |b 10 |
| 700 | 1 | _ | |a Koziej, Dorota |0 P:(DE-H253)PIP1031321 |b 11 |e Corresponding author |
| 773 | _ | _ | |a 10.1021/acsnano.5c02875 |g Vol. 19, no. 28, p. 25710 - 25719 |0 PERI:(DE-600)2383064-5 |n 28 |p 25710 - 25719 |t ACS nano |v 19 |y 2025 |x 1936-0851 |
| 856 | 4 | _ | |y OpenAccess |u https://bib-pubdb1.desy.de/record/636202/files/PDF-file.pdf |
| 856 | 4 | _ | |y OpenAccess |x pdfa |u https://bib-pubdb1.desy.de/record/636202/files/PDF-file.pdf?subformat=pdfa |
| 909 | C | O | |o oai:bib-pubdb1.desy.de:636202 |p openaire |p open_access |p driver |p VDB |p ec_fundedresources |p dnbdelivery |
| 910 | 1 | _ | |a Deutsches Elektronen-Synchrotron |0 I:(DE-588b)2008985-5 |k DESY |b 0 |6 P:(DE-H253)PIP1083268 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 0 |6 P:(DE-H253)PIP1083268 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 1 |6 P:(DE-H253)PIP1092080 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 2 |6 P:(DE-H253)PIP1098796 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 3 |6 P:(DE-H253)PIP1083208 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 4 |6 P:(DE-H253)PIP1090769 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 5 |6 P:(DE-H253)PIP1085597 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 6 |6 P:(DE-H253)PIP1085745 |
| 910 | 1 | _ | |a European XFEL |0 I:(DE-588)1043621512 |k XFEL.EU |b 6 |6 P:(DE-H253)PIP1085745 |
| 910 | 1 | _ | |a Deutsches Elektronen-Synchrotron |0 I:(DE-588b)2008985-5 |k DESY |b 7 |6 P:(DE-H253)PIP1010723 |
| 910 | 1 | _ | |a Deutsches Elektronen-Synchrotron |0 I:(DE-588b)2008985-5 |k DESY |b 8 |6 P:(DE-H253)PIP1100821 |
| 910 | 1 | _ | |a External Institute |0 I:(DE-HGF)0 |k Extern |b 11 |6 P:(DE-H253)PIP1031321 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Materie |l Von Materie zu Materialien und Leben |1 G:(DE-HGF)POF4-630 |0 G:(DE-HGF)POF4-632 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-600 |4 G:(DE-HGF)POF |v Materials – Quantum, Complex and Functional Materials |x 0 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Materie |l Großgeräte: Materie |1 G:(DE-HGF)POF4-6G0 |0 G:(DE-HGF)POF4-6G3 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-600 |4 G:(DE-HGF)POF |v PETRA III (DESY) |x 1 |
| 914 | 1 | _ | |y 2025 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |d 2025-01-07 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |d 2025-01-07 |
| 915 | _ | _ | |a Creative Commons Attribution CC BY 4.0 |0 LIC:(DE-HGF)CCBY4 |2 HGFVOC |
| 915 | _ | _ | |a IF >= 15 |0 StatID:(DE-HGF)9915 |2 StatID |b ACS NANO : 2022 |d 2025-01-07 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |d 2025-01-07 |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0113 |2 StatID |b Science Citation Index Expanded |d 2025-01-07 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |d 2025-01-07 |
| 915 | _ | _ | |a OpenAccess |0 StatID:(DE-HGF)0510 |2 StatID |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b ACS NANO : 2022 |d 2025-01-07 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0160 |2 StatID |b Essential Science Indicators |d 2025-01-07 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Clarivate Analytics Master Journal List |d 2025-01-07 |
| 920 | 1 | _ | |0 I:(DE-H253)HAS-User-20120731 |k DOOR ; HAS-User |l DOOR-User |x 0 |
| 920 | 1 | _ | |0 I:(DE-H253)FS-PETRA-D-20210408 |k FS-PETRA-D |l PETRA-D |x 1 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a UNRESTRICTED |
| 980 | _ | _ | |a I:(DE-H253)HAS-User-20120731 |
| 980 | _ | _ | |a I:(DE-H253)FS-PETRA-D-20210408 |
| 980 | 1 | _ | |a FullTexts |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|