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@ARTICLE{Loemker:624906,
      author       = {Loemker, Patrick and Degerman, David and Goodwin,
                      Christopher and Shipilin, Mikhail and Amann, Peter and
                      Rodrigues, Gabriel L. S. and Garcia-Martinez, Fernando and
                      Rameshan, Raffael and Gladh, Joergen and Wang, Hsin-Yi and
                      Soldemo, Markus and Holm, Alexander and Tober, Steffen and
                      Schober, Jan-Christian and Jacobse, Leon and Vonk, Vedran
                      and Gleißner, Robert and Noei, Heshmat and Hegedues, Zoltan
                      and Stierle, Andreas and Schlueter, Christoph and Nilsson,
                      Anders},
      title        = {{I}n-situ probing of the {F}ischer-{T}ropsch reaction on
                      {C}o single crystal surfaces up to 1 bar},
      journal      = {Nature Communications},
      volume       = {16},
      number       = {1},
      issn         = {2041-1723},
      address      = {[London]},
      publisher    = {Springer Nature},
      reportid     = {PUBDB-2025-00982},
      pages        = {1005},
      year         = {2025},
      abstract     = {The surface chemistry of the Fischer-Tropsch catalytic
                      reaction over Co hasstill several unknows. Here, we report
                      an in-situ X-ray photoelectron spectro-scopy study of Co
                      0001$ð$ Þ and Co(1014), and in-situ high energy surface
                      X-raydiffraction of Co 0001$ð$ Þ, during the
                      Fischer-Tropsch reaction at 0.15 bar - 1 barand 406 K - 548
                      K in a H$_2$/CO gas mixture. We find that these Co
                      surfacesremain metallic under all conditions and that the
                      coverage of chemisorbedspecies ranges from 0.4–1.7
                      monolayers depending on pressure and tem-perature. The
                      adsorbates include CO on-top, C/-C$_x$H$_y$ and various
                      longerhydrocarbon molecules, indicating a rate-limiting
                      direct CO dissociationpathway and that only hydrocarbon
                      species participate in the chain growth.The accumulation of
                      hydrocarbon species points to the termination step
                      beingrate-limiting also. Furthermore, we demonstrate that
                      the intermediate surfacespecies are highly dynamic,
                      appearing and disappearing with time delays afterrapid
                      changes in the reactants’ composition.},
      cin          = {FS-NL},
      ddc          = {500},
      cid          = {I:(DE-H253)FS-NL-20120731},
      pnm          = {632 - Materials – Quantum, Complex and Functional
                      Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
                      SWEDEN-DESY - SWEDEN-DESY Collaboration
                      $(2020_Join2-SWEDEN-DESY)$ / CALIPSOplus - Convenient Access
                      to Light Sources Open to Innovation, Science and to the
                      World (730872)},
      pid          = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
                      $G:(DE-HGF)2020_Join2-SWEDEN-DESY$ / G:(EU-Grant)730872},
      experiment   = {EXP:(DE-H253)P-P22-20150101 / EXP:(DE-H253)P-P21.1-20150101
                      / EXP:(DE-H253)Nanolab-02-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:39856064},
      UT           = {WOS:001406369400023},
      doi          = {10.1038/s41467-025-56082-8},
      url          = {https://bib-pubdb1.desy.de/record/624906},
}