TY  - JOUR
AU  - Bicalho, Hudson A.
AU  - Copeman, Christopher
AU  - Barbosa, Helliomar P.
AU  - Rafael Donnarumma, P.
AU  - Davis, Zoey
AU  - Quezada-Novoa, Victor
AU  - Velazquez Garcia, Jose
AU  - Liu, Nan
AU  - Hemmer, Eva
AU  - Howarth, Ashlee J.
TI  - Synthesis, Characterization and Photophysical Properties of a New Family of Rare‐Earth Cluster‐Based Metal‐Organic Frameworks
JO  - Chemistry - a European journal
VL  - 30
IS  - 60
SN  - 0947-6539
CY  - Weinheim
PB  - Wiley-VCH
M1  - PUBDB-2025-00359
SP  - e202402363
PY  - 2024
AB  - In this work, nine new rare-earth metal–organic frameworks (RE-MOFs, where RE=Lu(III), Yb(III), Tm(III), Er(III), Ho(III), Dy(III), Tb(III), Gd(III), and Eu(III)) isostructural to Zr-MOF-808 are synthesized, characterized, and studied regarding their photophysical properties. Materials with high crystallinity and surface area are obtained from a reproducible synthetic procedure that involves the use of two fluorinated modulators. At the same time, these new RE-MOFs display tunable photoluminescent properties due to efficient linker-to-metal energy transfer promoted by the antenna effect, resulting in a series of RE-MOFs displaying lanthanoid-based emissions spanning the visible and near-infrared regions of the electromagnetic spectrum.
LB  - PUB:(DE-HGF)16
C6  - pmid:39105655
UR  - <Go to ISI:>//WOS:001318330800001
DO  - DOI:10.1002/chem.202402363
UR  - https://bib-pubdb1.desy.de/record/622522
ER  -