Journal Article

PUBDB-2025-00359

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Synthesis, Characterization and Photophysical Properties of a New Family of Rare‐Earth Cluster‐Based Metal‐Organic Frameworks

Bicalho, H. A. ; Copeman, C. ; Barbosa, H. P. ; Rafael Donnarumma, P. ; Davis, Z. ; Quezada-Novoa, V. ; Velazquez Garcia, J.Extern*XFEL.EU*DESY* ; Liu, N. ; Hemmer, E. ; Howarth, A. J. (Corresponding author)

2024
Wiley-VCH Weinheim

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Please use a persistent id in citations: doi:10.1002/chem.202402363  doi:10.3204/PUBDB-2025-00359

Abstract: In this work, nine new rare-earth metal–organic frameworks (RE-MOFs, where RE=Lu(III), Yb(III), Tm(III), Er(III), Ho(III), Dy(III), Tb(III), Gd(III), and Eu(III)) isostructural to Zr-MOF-808 are synthesized, characterized, and studied regarding their photophysical properties. Materials with high crystallinity and surface area are obtained from a reproducible synthetic procedure that involves the use of two fluorinated modulators. At the same time, these new RE-MOFs display tunable photoluminescent properties due to efficient linker-to-metal energy transfer promoted by the antenna effect, resulting in a series of RE-MOFs displaying lanthanoid-based emissions spanning the visible and near-infrared regions of the electromagnetic spectrum.

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Contributing Institute(s):

1. Strukturdynamik Chemischer Systeme (FS-SCS)

Research Program(s):

1. 632 - Materials – Quantum, Complex and Functional Materials (POF4-632) (POF4-632)
2. HIDSS-0002 - DASHH: Data Science in Hamburg - Helmholtz Graduate School for the Structure of Matter (2019_IVF-HIDSS-0002) (2019_IVF-HIDSS-0002)
3. 6G3 - PETRA III (DESY) (POF4-6G3) (POF4-6G3)

Experiment(s):

1. PETRA Beamline P11 (PETRA III)

Appears in the scientific report 2024

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Database coverage:
; ; ; Chemical Reactions ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; DEAL Wiley ; Ebsco Academic Search ; Essential Science Indicators ; IF < 5 ; Index Chemicus ; JCR ; Nationallizenz ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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