%0 Journal Article
%A Bicalho, Hudson A.
%A Copeman, Christopher
%A Barbosa, Helliomar P.
%A Rafael Donnarumma, P.
%A Davis, Zoey
%A Quezada-Novoa, Victor
%A Velazquez Garcia, Jose
%A Liu, Nan
%A Hemmer, Eva
%A Howarth, Ashlee J.
%T Synthesis, Characterization and Photophysical Properties of a New Family of Rare‐Earth Cluster‐Based Metal‐Organic Frameworks
%J Chemistry - a European journal
%V 30
%N 60
%@ 0947-6539
%C Weinheim
%I Wiley-VCH
%M PUBDB-2025-00359
%P e202402363
%D 2024
%X In this work, nine new rare-earth metal–organic frameworks (RE-MOFs, where RE=Lu(III), Yb(III), Tm(III), Er(III), Ho(III), Dy(III), Tb(III), Gd(III), and Eu(III)) isostructural to Zr-MOF-808 are synthesized, characterized, and studied regarding their photophysical properties. Materials with high crystallinity and surface area are obtained from a reproducible synthetic procedure that involves the use of two fluorinated modulators. At the same time, these new RE-MOFs display tunable photoluminescent properties due to efficient linker-to-metal energy transfer promoted by the antenna effect, resulting in a series of RE-MOFs displaying lanthanoid-based emissions spanning the visible and near-infrared regions of the electromagnetic spectrum.
%F PUB:(DE-HGF)16
%9 Journal Article
%$ pmid:39105655
%U <Go to ISI:>//WOS:001318330800001
%R 10.1002/chem.202402363
%U https://bib-pubdb1.desy.de/record/622522