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| 001 | 606717 | ||
| 005 | 20250723171724.0 | ||
| 024 | 7 | _ | |a 10.1021/jacs.4c02163 |2 doi |
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| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Scholz, Alexander S. |0 P:(DE-HGF)0 |b 0 |
| 245 | _ | _ | |a Tetramerization of BEB-Doped Phenalenyls to Obtain (BE)$_8$-[16]Annulenes (E = N, O) |
| 260 | _ | _ | |a Washington, DC |c 2024 |b ACS Publications |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1716370822_1902 |2 PUB:(DE-HGF) |
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| 500 | _ | _ | |a Waiting for fulltext |
| 520 | _ | _ | |a Two (BE)8-[16] annulenes were prepared and fully characterized by experimental and quantum-chemical means (1,E =N;2, E=O). The 1,8-naphthalenediyl-bridged diborane(6)3 served as their common starting material, which was treated with [Al(NH$_3$)$_6$]Cl$_3$ to form 1 (91%yield) or with 1,8-naphthalenediboronic acid anhydride to form 2 (93%yield). As a result, the heteroannulenes 1 and 2 are supported by four aromatic “clamps” and may also be viewed as NH-or O-bridged cyclic tetramers of BNB-or BOB-doped phenalenyls. X-ray crystallography on mono-, di-, and tetra adducts 2*thf, 2*py$_2$, and 2*py$_4$ showed that 2 is an oligotopic Lewis acid (thf/py: tetrahydrofuran/pyridine donor). The applicability of 2 also as a Lewis basic ligand in coordination chemistry was demonstrated by the synthesis of the mononuclear Ag$^+$ complex [Ag(py)$_2$(2*py$_4$)]$^+$ and the dinuclear Pb$^{2+}$ complex 6. During the assembly of 6, the rearrangement of 2 led to the formation of two (BO)$_9$-macrocycles linked by two BOB-phenalenyls to form a nanom$eter-sized cage with four negatively charged, tetracoordinated B atoms. Both 1 and 2 show several redox waves in the cathodic regions of the cyclicvoltammograms. An in depth assessment of the consequences of electron injection on the aromaticity of 1 and 2was achieved by electronic structure calculations. 1 and 2 are proposed to exhibit aromatic switching capabilities in the [16]annulene motif. |
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| 542 | _ | _ | |i 2024-04-18 |2 Crossref |u https://doi.org/10.15223/policy-029 |
| 542 | _ | _ | |i 2024-04-18 |2 Crossref |u https://doi.org/10.15223/policy-037 |
| 542 | _ | _ | |i 2024-04-18 |2 Crossref |u https://doi.org/10.15223/policy-045 |
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| 700 | 1 | _ | |a Bolte, Michael |0 P:(DE-HGF)0 |b 1 |
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| 700 | 1 | _ | |a Peresypkina, Eugenia |0 P:(DE-H253)PIP1027099 |b 3 |
| 700 | 1 | _ | |a Lerner, Hans-Wolfram |0 0000-0003-1803-7947 |b 4 |
| 700 | 1 | _ | |a Anstöter, Cate S. |0 0000-0002-3412-2511 |b 5 |e Corresponding author |
| 700 | 1 | _ | |a Wagner, Matthias |0 P:(DE-H253)PIP1102807 |b 6 |e Corresponding author |
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