Home > Publications database > Guest-Induced Reversible Transformation between an Azulene-Based Pd$_2$L$_4$ Lantern-Shaped Cage and a Pd$_4$L$_8$ Tetrahedron > print

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100 1 _ |a Walther, Alexandre
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245 _ _ |a Guest-Induced Reversible Transformation between an Azulene-Based Pd$_2$L$_4$ Lantern-Shaped Cage and a Pd$_4$L$_8$ Tetrahedron
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520 _ _ |a Azulene,a bluestructuralisomerof naphthalene,isintroducedas the backbonefor a new familyof Pd(II)-basedself-assemblies.Threeorganicligands,equippedwithvaryingdonorgroups,producethree[Pd$_2$L$_4$] cagesof differentcavitydimensions.Unexpectedly,the additionof organicdisulfonategueststo thesmallestlantern-shapedcage(featuringpyridinedonors)led to arapidandquantitativetransformationto a distorted-tetrahedral[Pd4L8] species.On the contrary,[Pd$_2$L$_4$] cagesformedfromligandswithisoquinolinedonorseitherjust encapsulatedthe guestsorshowedno interaction.Thetetrahedralspeciescouldbe fullyrevertedbackto its original[Pd$_2$L$_4$] topologyby capturingthe guestby another,strongerbinding[Pd$_2$L´$_4$] coordinationcage,narcissis-ticallyself-sortingfromthe firstcage.Theazulenes,servingascoloredhydrocarbonbackbonesof minimalatomcount,allowone to followcage assemblyand guest-inducedtransformationby thenakedeye. Furthermore,we proposethat theirpeculiarelectronicstructureinfluencesthe system’sassemblybehavior.
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700 1 _ |a Regeni, Irene
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700 1 _ |a Holstein, Julian J.
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700 1 _ |a Clever, Guido
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773 _ _ |a 10.1021/jacs.3c09295
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856 4 _ |u https://bib-pubdb1.desy.de/record/599842/files/Published%20version.pdf
856 4 _ |y Published on 2023-11-14. Available in OpenAccess from 2024-11-14.
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856 4 _ |y Published on 2023-11-14. Available in OpenAccess from 2024-11-14.
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