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@ARTICLE{Walther:599842,
      author       = {Walther, Alexandre and Regeni, Irene and Holstein, Julian
                      J. and Clever, Guido},
      title        = {{G}uest-{I}nduced {R}eversible {T}ransformation between an
                      {A}zulene-{B}ased {P}d$_2${L}$_4$ {L}antern-{S}haped {C}age
                      and a {P}d$_4${L}$_8$ {T}etrahedron},
      journal      = {Journal of the American Chemical Society},
      volume       = {145},
      number       = {46},
      issn         = {0002-7863},
      address      = {Washington, DC},
      publisher    = {ACS Publications},
      reportid     = {PUBDB-2023-07559},
      pages        = {25365 - 25371},
      year         = {2023},
      abstract     = {Azulene,a bluestructuralisomerof naphthalene,isintroducedas
                      the backbonefor a new familyof
                      Pd(II)-basedself-assemblies.Threeorganicligands,equippedwithvaryingdonorgroups,producethree[Pd$_2$L$_4$]
                      cagesof differentcavitydimensions.Unexpectedly,the
                      additionof organicdisulfonategueststo
                      thesmallestlantern-shapedcage(featuringpyridinedonors)led to
                      arapidandquantitativetransformationto a
                      distorted-tetrahedral[Pd4L8] species.On the
                      contrary,[Pd$_2$L$_4$]
                      cagesformedfromligandswithisoquinolinedonorseitherjust
                      encapsulatedthe guestsorshowedno
                      interaction.Thetetrahedralspeciescouldbe fullyrevertedbackto
                      its original[Pd$_2$L$_4$] topologyby capturingthe guestby
                      another,strongerbinding[Pd$_2$L´$_4$]
                      coordinationcage,narcissis-ticallyself-sortingfromthe
                      firstcage.Theazulenes,servingascoloredhydrocarbonbackbonesof
                      minimalatomcount,allowone to followcage assemblyand
                      guest-inducedtransformationby thenakedeye. Furthermore,we
                      proposethat theirpeculiarelectronicstructureinfluencesthe
                      system’sassemblybehavior.},
      cin          = {DOOR ; HAS-User},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20200916
                      (I-20200916) / FS-Proposal: I-20210921 (I-20210921) /
                      FS-Proposal: I-20211437 (I-20211437)},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20200916 /
                      G:(DE-H253)I-20210921 / G:(DE-H253)I-20211437},
      experiment   = {EXP:(DE-H253)P-P11-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {37960849},
      UT           = {WOS:001108491500001},
      doi          = {10.1021/jacs.3c09295},
      url          = {https://bib-pubdb1.desy.de/record/599842},
}