Home > Publications database > The Sonogashira Coupling on Palladium Milling Balls—A new Reaction Pathway in Mechanochemistry > print

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024 7 _ |a 10.1002/anie.202301490
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100 1 _ |a Pickhardt, Wilm
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245 _ _ |a The Sonogashira Coupling on Palladium Milling Balls—A new Reaction Pathway in Mechanochemistry
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520 _ _ |a Utilizing direct mechanocatalytical conditions, the Sonogashira coupling was successfully performed on the surface of milling tools by using pure Pd and Pd coated steel balls. The optimization of co-catalyst forming additives led to a protocol, which generates quantitative yields under aerobic conditions for various substrates within as little as 90 minutes. Using state-of-the-art spectroscopic, diffractive, as well as in situ methods lead to the identification of a previously unknown and highly reactive complex of the co-catalyst copper. This new complex differs substantially from the known complexes in liquid phase Sonogashira couplings, proving that reaction pathways in mechanochemistry may differ from those in established synthetic procedures.
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700 1 _ |a Siegfried, Eleonora
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700 1 _ |a Fabig, Sven
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700 1 _ |a Rappen, Marisol Fabienne
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700 1 _ |a Etter, Martin
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700 1 _ |a Grätz, Sven
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700 1 _ |a Borchardt, Lars
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773 _ _ |a 10.1002/anie.202301490
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