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000597643 1001_ $$0P:(DE-H253)PIP1097121$$aPickhardt, Wilm$$b0
000597643 245__ $$aThe Sonogashira Coupling on Palladium Milling Balls—A new Reaction Pathway in Mechanochemistry
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000597643 520__ $$aUtilizing direct mechanocatalytical conditions, the Sonogashira coupling was successfully performed on the surface of milling tools by using pure Pd and Pd coated steel balls. The optimization of co-catalyst forming additives led to a protocol, which generates quantitative yields under aerobic conditions for various substrates within as little as 90 minutes. Using state-of-the-art spectroscopic, diffractive, as well as in situ methods lead to the identification of a previously unknown and highly reactive complex of the co-catalyst copper. This new complex differs substantially from the known complexes in liquid phase Sonogashira couplings, proving that reaction pathways in mechanochemistry may differ from those in established synthetic procedures. 
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000597643 7001_ $$aSiegfried, Eleonora$$b1
000597643 7001_ $$0P:(DE-H253)PIP1102222$$aFabig, Sven$$b2
000597643 7001_ $$0P:(DE-H253)PIP1102226$$aRappen, Marisol Fabienne$$b3
000597643 7001_ $$0P:(DE-H253)PIP1018552$$aEtter, Martin$$b4
000597643 7001_ $$0P:(DE-H253)PIP1097098$$aWohlgemuth, Maximilian$$b5
000597643 7001_ $$0P:(DE-H253)PIP1088156$$aGrätz, Sven$$b6
000597643 7001_ $$0P:(DE-HGF)0$$aBorchardt, Lars$$b7$$eCorresponding author
000597643 773__ $$0PERI:(DE-600)2011836-3$$a10.1002/anie.202301490$$gVol. 62, no. 27, p. e202301490$$n27$$pe202301490$$tAngewandte Chemie$$v62$$x1433-7851$$y2023
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