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| Home > Publications database > A Simple and Versatile Approach for the Low‐Temperature Synthesis of Transition Metal Phosphide Nanoparticles from Metal Chloride Complexes and P(SiMe$_3$)$_3$ > print |
| Home > Publications database > A Simple and Versatile Approach for the Low‐Temperature Synthesis of Transition Metal Phosphide Nanoparticles from Metal Chloride Complexes and P(SiMe$_3$)$_3$ > print |
| 001 | 596085 | ||
| 005 | 20250724132235.0 | ||
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| 100 | 1 | _ | |a Sodreau, Alexandre |0 P:(DE-H253)PIP1100985 |b 0 |
| 245 | _ | _ | |a A Simple and Versatile Approach for the Low‐Temperature Synthesis of Transition Metal Phosphide Nanoparticles from Metal Chloride Complexes and P(SiMe$_3$)$_3$ |
| 260 | _ | _ | |a Weinheim |c 2023 |b Wiley-VCH |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a Metal chloride complexes react with tris(trimethylsilyl)phosphine under mild condition to produce metal phosphide (TMP) nanoparticles (NPs), and chlorotrimethylsilane as a byproduct. The formation of Si–Cl bonds that are stronger than the starting M-Cl bonds acts as a driving force for the reaction. The potential of this strategy is illustrated through the preparation of ruthenium phosphide NPs using [RuCl$_2$(cymene)] and tris(trimethylsilyl)phosphine at 35 °C. Characterization with a combination of techniques including electron microscopy (EM), X-ray absorption spectroscopy (XAS), and solid-state nuclear magnetic resonance (NMR) spectroscopy, evidences the formation of small (diameter of 1.3 nm) and amorphous NPs with an overall Ru$_{50}$P$_{50}$ composition. Interestingly, these NPs can be easily immobilized on functional support materials, which is of great interest for potential applications in catalysis and electrocatalysis. Mo$_{50}$P$_{50}$ and Co$_{50}$P$_{50}$ NPs can also be synthesized following the same strategy. This approach is simple and versatile and paves the way toward the preparation of a wide range of transition metal phosphide nanoparticles under mild reaction conditions. |
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| 700 | 1 | _ | |a Menten, Julia |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Zenner, Johannes |0 P:(DE-H253)PIP1100977 |b 5 |
| 700 | 1 | _ | |a Terefenko, Nicole |0 P:(DE-HGF)0 |b 6 |
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| 700 | 1 | _ | |a Wiegand, Thomas |0 P:(DE-HGF)0 |b 8 |
| 700 | 1 | _ | |a Bordet, Alexis |0 P:(DE-H253)PIP1086018 |b 9 |e Corresponding author |
| 700 | 1 | _ | |a Leitner, Walter |0 P:(DE-HGF)0 |b 10 |e Corresponding author |
| 773 | _ | _ | |a 10.1002/adma.202306621 |g p. 2306621 |0 PERI:(DE-600)1474949-X |n 49 |p 2306621 |t Advanced materials |v 35 |y 2023 |x 0935-9648 |
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