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000596085 1001_ $$0P:(DE-H253)PIP1100985$$aSodreau, Alexandre$$b0
000596085 245__ $$aA Simple and Versatile Approach for the Low‐Temperature Synthesis of Transition Metal Phosphide Nanoparticles from Metal Chloride Complexes and P(SiMe$_3$)$_3$
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000596085 520__ $$aMetal chloride complexes react with tris(trimethylsilyl)phosphine under mild condition to produce metal phosphide (TMP) nanoparticles (NPs), and chlorotrimethylsilane as a byproduct. The formation of Si–Cl bonds that are stronger than the starting M-Cl bonds acts as a driving force for the reaction. The potential of this strategy is illustrated through the preparation of ruthenium phosphide NPs using [RuCl$_2$(cymene)] and tris(trimethylsilyl)phosphine at 35 °C. Characterization with a combination of techniques including electron microscopy (EM), X-ray absorption spectroscopy (XAS), and solid-state nuclear magnetic resonance (NMR) spectroscopy, evidences the formation of small (diameter of 1.3 nm) and amorphous NPs with an overall Ru$_{50}$P$_{50}$ composition. Interestingly, these NPs can be easily immobilized on functional support materials, which is of great interest for potential applications in catalysis and electrocatalysis. Mo$_{50}$P$_{50}$ and Co$_{50}$P$_{50}$ NPs can also be synthesized following the same strategy. This approach is simple and versatile and paves the way toward the preparation of a wide range of transition metal phosphide nanoparticles under mild reaction conditions.
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000596085 7001_ $$0P:(DE-HGF)0$$aZahedi, Hooman Ghazi$$b1
000596085 7001_ $$0P:(DE-HGF)0$$aDervişoğlu, Rıza$$b2
000596085 7001_ $$0P:(DE-H253)PIP1085988$$aKang, Liqun$$b3
000596085 7001_ $$0P:(DE-HGF)0$$aMenten, Julia$$b4
000596085 7001_ $$0P:(DE-H253)PIP1100977$$aZenner, Johannes$$b5
000596085 7001_ $$0P:(DE-HGF)0$$aTerefenko, Nicole$$b6
000596085 7001_ $$0P:(DE-H253)PIP1015325$$aDeBeer, Serena$$b7
000596085 7001_ $$0P:(DE-HGF)0$$aWiegand, Thomas$$b8
000596085 7001_ $$0P:(DE-H253)PIP1086018$$aBordet, Alexis$$b9$$eCorresponding author
000596085 7001_ $$0P:(DE-HGF)0$$aLeitner, Walter$$b10$$eCorresponding author
000596085 773__ $$0PERI:(DE-600)1474949-X$$a10.1002/adma.202306621$$gp. 2306621$$n49$$p2306621$$tAdvanced materials$$v35$$x0935-9648$$y2023
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