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@ARTICLE{Garg:491384,
      author       = {Garg, Akash and Almáši, Miroslav and Bednarčík, Jozef
                      and Sharma, Rishabh and Rao, Vikrant Singh and Panchal,
                      Priyanka and Jain, Ankur and Sharma, Anshu},
      title        = {{G}d({III}) metal-organic framework as an effective
                      humidity sensor and its hydrogen adsorption properties},
      journal      = {Chemosphere},
      volume       = {305},
      issn         = {0045-6535},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {PUBDB-2023-00122},
      pages        = {135467},
      year         = {2022},
      note         = {Waiting for fulltext},
      abstract     = {Metal-organic frameworks (MOFs) represent a class of
                      nanoporous materials built up by metal ions and organic
                      linkers with several interesting potential applications. The
                      present study described the synthesis and characterization
                      of Gd(III)-based MOF with the chemical composition
                      [Gd(BTC)(H$_2$O)]·DMF (BTC – trimesate, DMF =
                      N,N′-dimethylformamide), known as MOF-76(Gd) for hydrogen
                      adsorption/desorption capacity and humidity sensing
                      applications. The structure and morphology of as-synthesized
                      material were studied using powder X-ray diffraction,
                      scanning and transmission electron microscopy. The crystal
                      structure of MOF-76(Gd) consists of gadolinium (III) and
                      benzene-1,3,5-tricarboxylate ions, one coordinated aqua
                      ligand and one crystallization DMF molecule. The polymeric
                      framework of MOF-76(Gd) contains 1D sinusoidally shaped
                      channels with sizes of 6.7 × 6.7 Å propagating along c
                      crystallographic axis. The thermogravimetric analysis,
                      heating infrared spectroscopy and in-situ heating powder
                      X-ray diffraction experiments of the prepared framework
                      exhibited thermal stability up to 550 °C. Nitrogen
                      adsorption/desorption measurement at −196 °C showed a BET
                      surface area of 605 m$^2$ g$^{−1}$ and pore volume of 0.24
                      cm$^3$ g$^{−1}$. The maximal hydrogen storage capacity of
                      MOF-76(Gd) was 1.66 wt \% and 1.34 wt \% −196 °C and
                      −186 °C and pressure up to 1 bar, respectively. Finally,
                      the humidity sensing measurements (water adsorption
                      experiments) were performed, and the results indicate that
                      MOF-76(Gd) is a suitable material for moisture sensing
                      application with a fast response (11 s) and recovery time (2
                      s) in the relative humidity range of 11–98\%.},
      cin          = {DOOR ; HAS-User},
      ddc          = {333.7},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {899 - ohne Topic (POF4-899)},
      pid          = {G:(DE-HGF)POF4-899},
      experiment   = {EXP:(DE-H253)D-BW5-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {35764119},
      UT           = {WOS:000822569100005},
      doi          = {10.1016/j.chemosphere.2022.135467},
      url          = {https://bib-pubdb1.desy.de/record/491384},
}