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@ARTICLE{Karimi:461883,
      author       = {Karimi, Fahim and Riglos, María V. C. and Santoru, Antonio
                      and Hoell, Armin and Raghuwanshi, Vikram S. and Milanese,
                      Chiara and Bergemann, Nils and Pistidda, Claudio and Nolis,
                      Pau and Baro, Maria D. and Gizer, Gökhan and Le, Thi-Thu
                      and Pranzas, P. Klaus and Dornheim, Martin and Klassen,
                      Thomas and Schreyer, Andreas and Puszkiel, Julián},
      title        = {{I}n {S}itu {F}ormation of {T}i{B}$_2$ {N}anoparticles for
                      {E}nhanced {D}ehydrogenation/{H}ydrogenation {R}eaction
                      {K}inetics of {L}i{BH}$_4$ –{M}g{H}$_2$ as a {R}eversible
                      {S}olid-{S}tate {H}ydrogen {S}torage {C}omposite {S}ystem},
      journal      = {The journal of physical chemistry / C},
      volume       = {122},
      number       = {22},
      issn         = {1932-7455},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {PUBDB-2021-03147},
      pages        = {11671 - 11681},
      year         = {2018},
      abstract     = {To enhance the dehydrogenation/rehydrogenation kinetic
                      behavior of the LiBH$_4$–MgH$_2$ composite system, TiF$_4$
                      is used as an additive. The effect of this additive on the
                      hydride composite system has been studied by means of
                      laboratory and advanced synchrotron techniques.
                      Investigations on the synthesis and mechanism upon hydrogen
                      interaction show that the addition of TiF$_4$ to the
                      LiBH$_4$–MgH$_2$ composite system during the milling
                      procedure leads to the in situ formation of well-distributed
                      nanosized TiB$_2$ particles. These TiB$_2$ nanoparticles act
                      as nucleation agents for the formation of MgB$_2$ upon
                      dehydrogenation process of the hydride composite system. The
                      effect of TiB$_2$ nanoparticles is maintained upon cycling.},
      cin          = {FS-PS / Hereon},
      ddc          = {530},
      cid          = {I:(DE-H253)FS-PS-20131107 / I:(DE-H253)Hereon-20210428},
      pnm          = {899 - ohne Topic (POF4-899)},
      pid          = {G:(DE-HGF)POF4-899},
      experiment   = {EXP:(DE-H253)D-D3-20150101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000435020300009},
      doi          = {10.1021/acs.jpcc.8b02258},
      url          = {https://bib-pubdb1.desy.de/record/461883},
}