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000461883 1001_ $$0P:(DE-H253)PIP1008662$$aKarimi, Fahim$$b0$$eCorresponding author
000461883 245__ $$aIn Situ Formation of TiB$_2$ Nanoparticles for Enhanced Dehydrogenation/Hydrogenation Reaction Kinetics of LiBH$_4$ –MgH$_2$ as a Reversible Solid-State Hydrogen Storage Composite System 
000461883 260__ $$aWashington, DC$$bSoc.$$c2018
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000461883 520__ $$aTo enhance the dehydrogenation/rehydrogenation kinetic behavior of the LiBH$_4$–MgH$_2$ composite system, TiF$_4$ is used as an additive. The effect of this additive on the hydride composite system has been studied by means of laboratory and advanced synchrotron techniques. Investigations on the synthesis and mechanism upon hydrogen interaction show that the addition of TiF$_4$ to the LiBH$_4$–MgH$_2$ composite system during the milling procedure leads to the in situ formation of well-distributed nanosized TiB$_2$ particles. These TiB$_2$ nanoparticles act as nucleation agents for the formation of MgB$_2$ upon dehydrogenation process of the hydride composite system. The effect of TiB$_2$ nanoparticles is maintained upon cycling.   
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000461883 7001_ $$aRiglos, María V. C.$$b1
000461883 7001_ $$0P:(DE-H253)PIP1025196$$aSantoru, Antonio$$b2
000461883 7001_ $$0P:(DE-H253)PIP1008173$$aHoell, Armin$$b3
000461883 7001_ $$0P:(DE-H253)PIP1008351$$aRaghuwanshi, Vikram S.$$b4
000461883 7001_ $$aMilanese, Chiara$$b5
000461883 7001_ $$0P:(DE-H253)PIP1019882$$aBergemann, Nils$$b6
000461883 7001_ $$0P:(DE-H253)PIP1010848$$aPistidda, Claudio$$b7
000461883 7001_ $$00000-0003-2360-1709$$aNolis, Pau$$b8
000461883 7001_ $$aBaro, Maria D.$$b9
000461883 7001_ $$0P:(DE-H253)PIP1030053$$aGizer, Gökhan$$b10
000461883 7001_ $$0P:(DE-H253)PIP1093945$$aLe, Thi-Thu$$b11
000461883 7001_ $$0P:(DE-H253)PIP1008490$$aPranzas, P. Klaus$$b12
000461883 7001_ $$0P:(DE-H253)PIP1009603$$aDornheim, Martin$$b13
000461883 7001_ $$aKlassen, Thomas$$b14
000461883 7001_ $$0P:(DE-H253)PIP1006650$$aSchreyer, Andreas$$b15
000461883 7001_ $$0P:(DE-H253)PIP1013727$$aPuszkiel, Julián$$b16
000461883 773__ $$0PERI:(DE-600)2256522-X$$a10.1021/acs.jpcc.8b02258$$gVol. 122, no. 22, p. 11671 - 11681$$n22$$p11671 - 11681$$tThe journal of physical chemistry <Washington, DC> / C$$v122$$x1932-7455$$y2018
000461883 8564_ $$uhttps://bib-pubdb1.desy.de/record/461883/files/acs.jpcc.8b02258.pdf$$yPublished on 2018-05-09. Available in OpenAccess from 2019-05-09.
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