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000437589 0247_ $$2doi$$a10.1103/PhysRevResearch.2.023091
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000437589 1001_ $$0P:(DE-HGF)0$$aCampargue, Alain$$b0$$eCorresponding author
000437589 245__ $$aObservation of electric-quadrupole infrared transitions in water vapor
000437589 260__ $$aCollege Park, MD$$bAPS$$c2020
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000437589 520__ $$aMolecular absorption of infrared radiation is generally due to rovibrational electric-dipole transitions. Electric-quadrupole  transitions  may  still  occur,  but  they  are  typically  a  million  times  weaker  than  electric-dipoletransitions,  rendering  their  observation  extremely  challenging.  In  polyatomic  or  polar  diatomic  molecules,rovibrational quadrupole transitions have never been observed. Here, we report the direct detection of quadrupoletransitions  in  water  vapor.  The  detected  quadrupole  lines  have  intensity  largely  above  the  standard  dipoleintensity cutoff of spectroscopic databases and thus are important for accurate atmospheric and astronomicalremote sensing.
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000437589 7001_ $$0P:(DE-HGF)0$$aKassi, Samir$$b1
000437589 7001_ $$0P:(DE-H253)PIP1031546$$aYachmenev, Andrey$$b2
000437589 7001_ $$0P:(DE-HGF)0$$aKyuberis, Aleksandra A.$$b3
000437589 7001_ $$0P:(DE-H253)PIP1012175$$aKüpper, Jochen$$b4
000437589 7001_ $$0P:(DE-HGF)0$$aYurchenko, Sergei N.$$b5
000437589 773__ $$0PERI:(DE-600)3004165-X$$a10.1103/PhysRevResearch.2.023091$$p023091$$tPhysical review research$$v2$$x2643-1564$$y2020
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