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@ARTICLE{Wondraczek:409183,
      author       = {Wondraczek, Lothar and Pan, Zhiwen and Palenta, Theresia
                      and Erlebach, Andreas and Misture, Scott T. and Sierka,
                      Marek and Micoulaut, Matthieu and Hoppe, Uwe and Deubener,
                      Joachim and Greaves, G. Neville},
      title        = {{K}inetics of {D}ecelerated {M}elting},
      journal      = {Advanced science},
      volume       = {5},
      number       = {5},
      issn         = {2198-3844},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PUBDB-2018-03293},
      pages        = {1700850},
      year         = {2018},
      abstract     = {Melting presents one of the most prominent phenomena in
                      condensed matter science. Its microscopic understanding,
                      however, is still fragmented, ranging from simplistic theory
                      to the observation of melting point depressions. Here, a
                      multimethod experimental approach is combined with
                      computational simulation to study the microscopic mechanism
                      of melting between these two extremes. Crystalline
                      structures are exploited in which melting occurs into a
                      metastable liquid close to its glass transition temperature.
                      The associated sluggish dynamics concur with real‐time
                      observation of homogeneous melting. In‐depth information
                      on the structural signature is obtained from various
                      independent spectroscopic and scattering methods, revealing
                      a step‐wise nature of the transition before reaching the
                      liquid state. A kinetic model is derived in which the first
                      reaction step is promoted by local instability events, and
                      the second is driven by diffusive mobility. Computational
                      simulation provides further confirmation for the sequential
                      reaction steps and for the details of the associated
                      structural dynamics. The successful quantitative modeling of
                      the low‐temperature decelerated melting of zeolite
                      crystals, reconciling homogeneous with heterogeneous
                      processes, should serve as a platform for understanding the
                      inherent instability of other zeolitic structures, as well
                      as the prolific and more complex nanoporous metal–organic
                      frameworks.},
      cin          = {DOOR},
      ddc          = {500},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (POF3-622) / FS-Proposal: I-20140514
                      (I-20140514)},
      pid          = {G:(DE-HGF)POF3-6G3 / G:(DE-H253)I-20140514},
      experiment   = {EXP:(DE-H253)P-P02.1-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:29876211},
      UT           = {WOS:000435852800014},
      doi          = {10.1002/advs.201700850},
      url          = {https://bib-pubdb1.desy.de/record/409183},
}