000409183 001__ 409183
000409183 005__ 20250729164645.0
000409183 0247_ $$2doi$$a10.1002/advs.201700850
000409183 0247_ $$2datacite_doi$$a10.3204/PUBDB-2018-03293
000409183 0247_ $$2altmetric$$aaltmetric:33842422
000409183 0247_ $$2pmid$$apmid:29876211
000409183 0247_ $$2WOS$$aWOS:000435852800014
000409183 0247_ $$2openalex$$aopenalex:W2790513886
000409183 037__ $$aPUBDB-2018-03293
000409183 041__ $$aEnglish
000409183 082__ $$a500
000409183 1001_ $$0P:(DE-H253)PIP1024214$$aWondraczek, Lothar$$b0$$eCorresponding author
000409183 245__ $$aKinetics of Decelerated Melting
000409183 260__ $$aWeinheim$$bWiley-VCH$$c2018
000409183 3367_ $$2DRIVER$$aarticle
000409183 3367_ $$2DataCite$$aOutput Types/Journal article
000409183 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1536075330_32342
000409183 3367_ $$2BibTeX$$aARTICLE
000409183 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000409183 3367_ $$00$$2EndNote$$aJournal Article
000409183 520__ $$aMelting presents one of the most prominent phenomena in condensed matter science. Its microscopic understanding, however, is still fragmented, ranging from simplistic theory to the observation of melting point depressions. Here, a multimethod experimental approach is combined with computational simulation to study the microscopic mechanism of melting between these two extremes. Crystalline structures are exploited in which melting occurs into a metastable liquid close to its glass transition temperature. The associated sluggish dynamics concur with real‐time observation of homogeneous melting. In‐depth information on the structural signature is obtained from various independent spectroscopic and scattering methods, revealing a step‐wise nature of the transition before reaching the liquid state. A kinetic model is derived in which the first reaction step is promoted by local instability events, and the second is driven by diffusive mobility. Computational simulation provides further confirmation for the sequential reaction steps and for the details of the associated structural dynamics. The successful quantitative modeling of the low‐temperature decelerated melting of zeolite crystals, reconciling homogeneous with heterogeneous processes, should serve as a platform for understanding the inherent instability of other zeolitic structures, as well as the prolific and more complex nanoporous metal–organic frameworks.
000409183 536__ $$0G:(DE-HGF)POF3-6G3$$a6G3 - PETRA III (POF3-622)$$cPOF3-622$$fPOF III$$x0
000409183 536__ $$0G:(DE-H253)I-20140514$$aFS-Proposal: I-20140514 (I-20140514)$$cI-20140514$$x1
000409183 588__ $$aDataset connected to CrossRef
000409183 693__ $$0EXP:(DE-H253)P-P02.1-20150101$$1EXP:(DE-H253)PETRAIII-20150101$$6EXP:(DE-H253)P-P02.1-20150101$$aPETRA III$$fPETRA Beamline P02.1$$x0
000409183 7001_ $$0P:(DE-HGF)0$$aPan, Zhiwen$$b1
000409183 7001_ $$0P:(DE-HGF)0$$aPalenta, Theresia$$b2
000409183 7001_ $$0P:(DE-HGF)0$$aErlebach, Andreas$$b3
000409183 7001_ $$0P:(DE-HGF)0$$aMisture, Scott T.$$b4
000409183 7001_ $$0P:(DE-HGF)0$$aSierka, Marek$$b5
000409183 7001_ $$0P:(DE-H253)PIP1031558$$aMicoulaut, Matthieu$$b6
000409183 7001_ $$0P:(DE-H253)PIP1009924$$aHoppe, Uwe$$b7
000409183 7001_ $$0P:(DE-HGF)0$$aDeubener, Joachim$$b8
000409183 7001_ $$0P:(DE-HGF)0$$aGreaves, G. Neville$$b9
000409183 773__ $$0PERI:(DE-600)2808093-2$$a10.1002/advs.201700850$$gVol. 5, no. 5, p. 1700850 -$$n5$$p1700850$$tAdvanced science$$v5$$x2198-3844$$y2018
000409183 8564_ $$uhttps://bib-pubdb1.desy.de/record/409183/files/advsc2018_suppl_5_201700850.pdf$$yRestricted
000409183 8564_ $$uhttps://bib-pubdb1.desy.de/record/409183/files/advsc2018_5_201700850.pdf$$yOpenAccess
000409183 8564_ $$uhttps://bib-pubdb1.desy.de/record/409183/files/advsc2018_suppl_5_201700850.gif?subformat=icon$$xicon$$yRestricted
000409183 8564_ $$uhttps://bib-pubdb1.desy.de/record/409183/files/advsc2018_suppl_5_201700850.jpg?subformat=icon-1440$$xicon-1440$$yRestricted
000409183 8564_ $$uhttps://bib-pubdb1.desy.de/record/409183/files/advsc2018_suppl_5_201700850.jpg?subformat=icon-180$$xicon-180$$yRestricted
000409183 8564_ $$uhttps://bib-pubdb1.desy.de/record/409183/files/advsc2018_suppl_5_201700850.jpg?subformat=icon-640$$xicon-640$$yRestricted
000409183 8564_ $$uhttps://bib-pubdb1.desy.de/record/409183/files/advsc2018_suppl_5_201700850.pdf?subformat=pdfa$$xpdfa$$yRestricted
000409183 8564_ $$uhttps://bib-pubdb1.desy.de/record/409183/files/advsc2018_5_201700850.gif?subformat=icon$$xicon$$yOpenAccess
000409183 8564_ $$uhttps://bib-pubdb1.desy.de/record/409183/files/advsc2018_5_201700850.jpg?subformat=icon-1440$$xicon-1440$$yOpenAccess
000409183 8564_ $$uhttps://bib-pubdb1.desy.de/record/409183/files/advsc2018_5_201700850.jpg?subformat=icon-180$$xicon-180$$yOpenAccess
000409183 8564_ $$uhttps://bib-pubdb1.desy.de/record/409183/files/advsc2018_5_201700850.jpg?subformat=icon-640$$xicon-640$$yOpenAccess
000409183 8564_ $$uhttps://bib-pubdb1.desy.de/record/409183/files/advsc2018_5_201700850.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000409183 909CO $$ooai:bib-pubdb1.desy.de:409183$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
000409183 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1024214$$aExternes Institut$$b0$$kExtern
000409183 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1031558$$aExternes Institut$$b6$$kExtern
000409183 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1009924$$aExternes Institut$$b7$$kExtern
000409183 9131_ $$0G:(DE-HGF)POF3-622$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF3-6G3$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vFacility topic: Research on Matter with Brilliant Light Sources$$x0
000409183 9141_ $$y2018
000409183 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000409183 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000409183 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bADV SCI : 2015
000409183 915__ $$0StatID:(DE-HGF)9905$$2StatID$$aIF >= 5$$bADV SCI : 2015
000409183 915__ $$0StatID:(DE-HGF)0501$$2StatID$$aDBCoverage$$bDOAJ Seal
000409183 915__ $$0StatID:(DE-HGF)0500$$2StatID$$aDBCoverage$$bDOAJ
000409183 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000409183 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000409183 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences
000409183 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000409183 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bThomson Reuters Master Journal List
000409183 9201_ $$0I:(DE-H253)HAS-User-20120731$$kDOOR$$lDOOR-User$$x0
000409183 980__ $$ajournal
000409183 980__ $$aVDB
000409183 980__ $$aI:(DE-H253)HAS-User-20120731
000409183 980__ $$aUNRESTRICTED
000409183 9801_ $$aFullTexts