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000398834 245__ $$aPhotodissociation of Aligned $\mathrm{CH_3I}$ and $\mathrm{C_{6}H_{3}F_{2}I}$ Molecules Probed with Time-Resolved Coulomb Explosion Imaging by Site-Selective XUV Ionization
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000398834 520__ $$aWe explore time-resolved Coulomb explosion induced by intense, extreme ultraviolet (XUV) femtosecond pulses from a free-electron laser as a method to image photo-induced molecular dynamics in two molecules, iodomethane and 2,6-difluoroiodobenzene. At an excitation wavelength of 267 nm, the dominant reaction pathway in both molecules is neutral dissociation via cleavage of the carbon–iodine bond. This allows investigating the influence of the molecular environment on the absorption of an intense, femtosecond XUV pulse and the subsequent Coulomb explosion process. We find that the XUV probe pulse induces local inner-shell ionization of atomic iodine in dissociating iodomethane, in contrast to non-selective ionization of all photofragments in difluoroiodobenzene. The results reveal evidence of electron transfer from methyl and phenyl moieties to a multiply charged iodine ion. In addition, indications for ultrafast charge rearrangement on the phenyl radical are found, suggesting that time-resolved Coulomb explosion imaging is sensitive to the localization of charge in extended molecules.
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000398834 536__ $$0G:(EU-Grant)641789$$aMEDEA - Molecular Electron Dynamics investigated by IntensE Fields and Attosecond Pulses (641789)$$c641789$$fH2020-MSCA-ITN-2014$$x3
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000398834 7001_ $$aLauer, Alexandra$$b13
000398834 7001_ $$aLee, Jason W. L.$$b14
000398834 7001_ $$aMüller, Maria$$b15
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000398834 7001_ $$aMullins, Terence$$b17
000398834 7001_ $$aRedlin, Harald$$b18
000398834 7001_ $$aSchirmel, Nora$$b19
000398834 7001_ $$aThøgersen, Jan$$b20
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000398834 7001_ $$aUlmer, Anatoli$$b25
000398834 7001_ $$aVallance, Claire$$b26
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000398834 7001_ $$aJohnsson, Per$$b28
000398834 7001_ $$0P:(DE-H253)PIP1012175$$aKüpper, Jochen$$b29
000398834 7001_ $$0P:(DE-H253)PIP1006803$$aRudenko, Artem$$b30
000398834 7001_ $$aRouzée, Arnaud$$b31
000398834 7001_ $$aStapelfeldt, Henrik$$b32
000398834 7001_ $$0P:(DE-H253)PIP1007320$$aRolles, Daniel$$b33$$eCorresponding author
000398834 7001_ $$0P:(DE-H253)PIP1014282$$aBoll, Rebecca$$b34$$eCorresponding author
000398834 773__ $$0PERI:(DE-600)2758684-4$$a10.1063/1.4998648$$gVol. 5, no. 1, p. 014301 -$$n1$$p014301 -$$tStructural dynamics$$v5$$x2329-7778$$y2018
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