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100 1 _ |a Wilkens, H.
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245 _ _ |a Post deposition annealing of epitaxial $\mathrm{Ce_{1−x}Pr_{x}O_{2-\delta}}$ films grown on Si(111)
260 _ _ |a Cambridge
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520 _ _ |a n this work the structural and morphological changes of Ce$_{1−x}$Pr$_{x}$O$_{2-\delta}$ (x= 0.20, 0.35 and 0.75) films grown on Si(111) due to post deposition annealing are investigated by low energy electron diffraction combined with a spot profile analysis. The surface of the oxide films exhibit mosaics with large terraces separated by monoatomic steps. It is shown that the Ce/Pr ratio and post deposition annealingtemperature can be used to tune the mosaic spread, terrace size and step height of the grains. The morphological changes are accompanied by a phase transition from a fluorite type lattice to a bixbyite structure. Furthermore, at high PDA temperatures a silicate formationvia a polycrystalline intermediate state is observed.
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700 1 _ |a Spieß, W.
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700 1 _ |a Zoellner, M. H.
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700 1 _ |a Niu, G.
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700 1 _ |a Schroeder, T.
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700 1 _ |a Wollschlaeger, Joachim
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773 _ _ |a 10.1039/C5CP01105A
|g Vol. 17, no. 15, p. 9991 - 9996
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