% IMPORTANT: The following is UTF-8 encoded. This means that in the presence % of non-ASCII characters, it will not work with BibTeX 0.99 or older. % Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or % “biber”. @ARTICLE{Klacsov:207189, author = {Klacsová, Mária and Karlovská, Janka and Uhríková, Daniela and Funari, Sergio de Souza and Balgavý, Pavol}, title = {{P}hase {B}ehavior of the {DOPE} + {DOPC} + {A}lkanol {S}ystem}, journal = {Soft matter}, volume = {10}, number = {31}, issn = {1744-6848}, address = {London}, publisher = {Royal Soc. of Chemistry}, reportid = {PUBDB-2015-01173}, pages = {5842 - 5848}, year = {2014}, note = {(c) The Royal Society of Chemistry. Post referee full text in progress.}, abstract = {Small- and wide-angle X-ray diffraction was used to study the effect of 1-alkanols, as simple models of general anesthetics, (abbreviation $C_{n}OH$, n = 8–18 is the even number of carbons in the aliphatic chain) on the lamellar to hexagonal $L\alpha \rightarrow H_{II}$ phase transition in the dioleoylphosphatidylethanolamine–dioleoylphosphatidylcholine = 3 : 1 mol/mol (DOPE + DOPC) system. All studied $C_{n}OHs$ were found to decrease the phase transition temperature of the DOPE + DOPC system in a $C_{n}OH$ chain length and concentration dependent manner and thus promote the formation of the $H_{II}$ phase. Anesthetically active $C_{8}OH$ and $C_{10}OH$ were found to decrease the lattice parameter $\mathit{d}$ of the $L\alpha$ phase, however longer non-anesthetic CnOHs increased the parameter $\mathit{d}$; this effect being more pronounced with increasing $C_{n}OH$ concentration. The lattice parameter $\mathit{a}$ of the $H_{II}$ phase was decreased in the presence of all $C_{n}OHs$, even at the lowest concentrations studied. In the scope of the indirect mechanism of general anesthesia observed changes in the lattice parameter $\mathit{d}$ (reflecting changes in the bilayer thickness) due to the intercalation of $C_{8}OH$ and $C_{10}OH$ might induce changes in the activity of integral membrane proteins engaged in neuronal pathways.}, cin = {DOOR / FS-DO / FS-PEX}, ddc = {530}, cid = {I:(DE-H253)HAS-User-20120731 / I:(DE-H253)FS-DO-20120731 / I:(DE-H253)FS-PEX-20130206}, pnm = {DORIS Beamline A2 (POF2-54G13)}, pid = {G:(DE-H253)POF2-A2-20130405}, experiment = {EXP:(DE-H253)D-A2-20150101}, typ = {PUB:(DE-HGF)16}, UT = {WOS:000340428700021}, pubmed = {pmid:24980804}, doi = {10.1039/C4SM00530A}, url = {https://bib-pubdb1.desy.de/record/207189}, }