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100 1 _ |a Niekiel, Felicitas
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245 _ _ |a Aluminum-1,4-cyclohexanedicarboxylates: High-Throughput and Temperature-Dependent in Situ EDXRD Studies
260 _ _ |a Washington, DC
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520 _ _ |a Exploring the use of the flexible aliphatic 1,4-cyclohexanedicarboxylic acid (H2CDC) as linker molecule in Al-MOF synthesis, two new compounds were discovered. The layered compound 1 is built from chains of corner-sharing AlO6-polyhedra and cis-CDC, while the microporous MIL-53 analogue CAU-13 (2) contains the same inorganic building unit as 1 but trans-CDC linker molecules in two different conformations. In addition to the detailed characterization of both compounds, the crystallization of 2 was investigated with temperature-dependent in situ EDXRD.
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700 1 _ |a Ackermann, Maximilian
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700 1 _ |a Guerrier, Paul
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700 1 _ |a Rothkirch, André
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700 1 _ |a Stock, Norbert
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773 _ _ |a 10.1021/ic400825b
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