2026-06-16 12:33 |
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2026-06-15 10:45 |
[PUBDB-2026-01828]
Journal Article
Artemov, V. ; Babiy, S. ; Teng, Y. ; et al
All-water supercapacitor enabled by 1-nm clay channels
Water confined to channels one nanometer thick exhibits electrochemicalbehavior distinct from bulk water, including enhanced protonic conductivityand large dielectric anisotropy.Here, we exploit these characteristics to designa scalable electrochemical energy storage system-a “blue capacitor”-constructedentirely from naturally abundant materials. By assembling layeredclays and conductive graphene, we produce 1-nm-thick channels in whichconfined water acts as the sole electrolyte. [...]
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2026-06-10 14:35 |
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2026-06-10 12:15 |
[PUBDB-2026-01790]
Journal Article
Karger, S. ; Drösemeier, E. ; Virovets, A. ; et al
Something germane about germanium: facile access to $Ge_10$ adamantane
The all-germanium adamantane (Me$_3$SiGe)$_4$(GeMe$_2$)$_6$ (2) was synthesized from its isomer (Me$_3$GeSi)$_4$(GeMe$_2$)$_6$ (1) via sila-Wagner-Meerwein rearrangement (overall four steps starting from commercial Me$_2$GeCl$_2$, Si$_2$Cl$_6$, and [nBu$_4$N]Cl). The molecular structures of 1 and 2 were characterized by single-crystal X-ray diffraction; a plausible mechanistic scenario is postulated based on quantum-chemical calculations..
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2026-06-10 11:54 |
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2026-06-10 11:51 |
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2026-06-10 11:49 |
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2026-06-10 11:46 |
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2026-06-10 11:40 |
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2026-06-10 11:38 |
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