Documents in process

Manganese plays an important role in redox catalysis using zeolites as inorganic support materials, but the formation of the preferred redox manganese species (framework or extraframework) is still not well understood. Herein, the influence of the amount of manganese together with conventional and microwave-assisted hydrothermal synthesis paths on the formation of manganese species within the zeolite silicalite-1 (S-1) with MFI structure was investigated. [...]

We present a theoretical investigation of the molecular-frame photoelectron angular distribution (MF-PAD) resulting from the inner-shell photoionization of fixed-in-space CO molecules with elliptically polarized light. The MSXα output program, originally written for linearly polarized light, was changed in order to calculate the MF-PAD for circularly and elliptically polarized light. [...]

Amphiphilic monolayers formed at the soft air/liquid interface are easy-to-handle and versatile model systems for material and life sciences. Helmuth Möhwald was one of the pioneers in this field. [...]

An intrinsic knowledge gap between current understandings obtained experimentally and the underlying working or degradation mechanisms of rechargeable lithium batteries still remains, giving direct rise to application challenges, e.g., safety issues, predicaments in identifying performance-aging factors and dilemmas in guiding further research directions. Against this background, non-destructive and three-dimensional (synchrotron) X-ray tomography that guarantees a direct visual access to inner electrodes has been employed herein to: in-situ record the evolution of internal short circuits; characterize the behaviors of widely employed separators; investigate the morphological evolution of Li electrodes under different cycling conditions; and study the degradation mechanisms of Li/carbon cells. [...]