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@ARTICLE{Landt:92781,
      author       = {Landt, L. and Staiger, M. and Wolter, D. and Klünder, K.
                      and Zimmermann, P. and Willey, T. M. and van Buuren, T. and
                      Brehmer, D. and Schreiner, P. R. and Tkachenko, B. A. and
                      Fokin, A. A. and Möller, T. and Bostedt, C. and DESY},
      title        = {{T}he influence of a single thiol group on the electronic
                      and optical properties of the smallest diamond adamantane},
      journal      = {The journal of chemical physics},
      volume       = {132},
      issn         = {0021-9606},
      address      = {Melville, NY},
      publisher    = {American Institute of Physics},
      reportid     = {PHPPUBDB-12496},
      pages        = {024710},
      year         = {2010},
      abstract     = {At the nanoscale, the surface becomes pivotal for the
                      properties of semiconductors due to an increased
                      surface-to-bulk ratio. Surface functionalization is a means
                      to include semiconductor nanocrystals into devices. In this
                      comprehensive experimental study we determine in detail the
                      effect of a single thiol functional group on the electronic
                      and optical properties of the hydrogen-passivated
                      nanodiamond adamantane. We find that the optical properties
                      of the diamondoid are strongly affected due to a drastic
                      change in the occupied states. Compared to adamantane, the
                      optical gap in adamantane-1-thiol is lowered by
                      approximately 0.6 eV and UV luminescence is quenched. The
                      lowest unoccupied states remain delocalized at the cluster
                      surface leaving the diamondoid's negative electron affinity
                      intact.},
      cin          = {HASYLAB},
      ddc          = {540},
      cid          = {$I:(DE-H253)HASYLAB_-2012_-20130307$},
      pnm          = {DORIS Beamline I (POF2-54G13) / FS-Proposal: II-20080161
                      (II-20080161)},
      pid          = {G:(DE-H253)POF2-I-20130405 / G:(DE-H253)II-20080161},
      experiment   = {EXP:(DE-H253)D-I-20150101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:20095697},
      UT           = {WOS:000273689000043},
      doi          = {10.1063/1.3280388},
      url          = {https://bib-pubdb1.desy.de/record/92781},
}