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000090449 1001_ $$aPouzet, E.$$b0
000090449 1101_ $$aDESY$$bExperiments with synchrotron radiation
000090449 245__ $$aHomeotropic Alignment of a Discotic Liquid Crystal Induced by a Sacrificial Layer
000090449 260__ $$aWashington, DC$$bSoc.$$c2009
000090449 300__ $$a14398-14406
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000090449 440_0 $$0PERI:(DE-600)2256522-X$$aJ. Phys. Chem. C$$v113$$x1932-7447$$y32
000090449 500__ $$3Converted on 2013-05-30 13:57$$a© American Chemical Society; Post referee fulltext in progress; Embargo 12 months from publication
000090449 500__ $$3Converted on 2013-06-21 19:20
000090449 520__ $$aA convenient method to induce face-on orientation of an alkoxy phtalocyanine discotic mesogen is described.The alignment is imposed by the confinement of the discotic thin films with a top sacrificial polymer layerthat is easily removed by washing with a selective solvent, after thermal annealing. Thin films have beencharacterized by optical and atomic force microscopy, UV-Vis absorption spectroscopy, and grazing incidencewide angle X-ray scattering. The data converge in showing the central role of the sacrificial layer in promotingalignment with the planar molecules orienting parallel to the substrate in an essentially homeotropic arrangementover large lateral length scales and the persistence of this desirable alignment after removal of the layer
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000090449 7001_ $$aDe Cupere, V.$$b1
000090449 7001_ $$aHeintz, C.$$b2
000090449 7001_ $$aAndreasen, J. W.$$b3
000090449 7001_ $$aBreiby, D. W.$$b4
000090449 7001_ $$aNielsen, M. M.$$b5
000090449 7001_ $$aViville, P.$$b6
000090449 7001_ $$aLazzaroni, R.$$b7
000090449 7001_ $$aGbabode, G.$$b8
000090449 7001_ $$0P:(DE-HGF)0$$aGeerts, Y. H.$$b9$$eCorresponding author
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