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@ARTICLE{Solozhenko:88683,
author = {Solozhenko, V. L. and Kurakevych, O. O. and Sokolov, P. S.
and Baranov, A. N. and DESY},
title = {{K}inetics of the wurtzite-to-rock-salt phase
transformation in {Z}n{O} at high pressure},
journal = {The journal of physical chemistry / A},
volume = {115},
issn = {1089-5639},
address = {Washington, DC},
publisher = {Soc.},
reportid = {PHPPUBDB-16823},
pages = {4354-4358},
year = {2011},
abstract = {Kinetics of the wurtzite-to-rock-salt transformation in ZnO
has been studied in the 5-7 GPa pressure range at
temperatures below the activation of diffusion processes.
The detailed analysis of non-isothermal experimental data
using the general evolution equation describing the kinetics
of direct phase transformations in solids allowed us to
study the kinetic particularities of both nucleation and
growth of the rock-salt phase in parent wurtzite ZnO. The
main rate-limiting processes are thermally activated
nucleation (E(N) = 383 kJ mol(-1) at 6.9 GPa) and thermally
nonactivated (most probably quasi-martensitic) growth (k(G)
= 0.833 min(-1) at 6.9 GPa). The high impact of thermal
deactivation of nucleation places has been evidenced in the
case of slow heating, which indirectly indicates that the
rs-ZnO nucleation places are mainly produced by
pressure-induced stresses in the parent phase.},
keywords = {Diffusion / Kinetics / Phase Transition / Pressure / Salts:
chemistry / Temperature / Zinc Oxide: chemistry / Salts (NLM
Chemicals) / Zinc Oxide (NLM Chemicals)},
cin = {HASYLAB},
ddc = {530},
cid = {$I:(DE-H253)HASYLAB_-2012_-20130307$},
pnm = {DORIS Beamline F2.1 (POF2-54G13) / FS-Proposal: I-20100021
EC (I-20100021-EC)},
pid = {G:(DE-H253)POF2-F2.1-20130405 / G:(DE-H253)I-20100021-EC},
experiment = {EXP:(DE-H253)D-F2.1-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:21488624},
UT = {WOS:000289824500026},
doi = {10.1021/jp201544f},
url = {https://bib-pubdb1.desy.de/record/88683},
}