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000088683 1001_ $$aSolozhenko, V. L.
000088683 1101_ $$aDESY$$bExperiments with synchrotron radiation
000088683 245__ $$aKinetics of the wurtzite-to-rock-salt phase transformation in ZnO at high pressure
000088683 260__ $$aWashington, DC$$bSoc.$$c2011
000088683 300__ $$a4354-4358
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000088683 440_0 $$0PERI:(DE-600)2006031-2$$aJ. Phys. Chem. A$$v115$$x1089-5639$$y17
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000088683 520__ $$aKinetics of the wurtzite-to-rock-salt transformation in ZnO has been studied in the 5-7 GPa pressure range at temperatures below the activation of diffusion processes. The detailed analysis of non-isothermal experimental data using the general evolution equation describing the kinetics of direct phase transformations in solids allowed us to study the kinetic particularities of both nucleation and growth of the rock-salt phase in parent wurtzite ZnO. The main rate-limiting processes are thermally activated nucleation (E(N) = 383 kJ mol(-1) at 6.9 GPa) and thermally nonactivated (most probably quasi-martensitic) growth (k(G) = 0.833 min(-1) at 6.9 GPa). The high impact of thermal deactivation of nucleation places has been evidenced in the case of slow heating, which indirectly indicates that the rs-ZnO nucleation places are mainly produced by pressure-induced stresses in the parent phase.
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000088683 650_2 $$2MeSH$$aDiffusion
000088683 650_2 $$2MeSH$$aKinetics
000088683 650_2 $$2MeSH$$aPhase Transition
000088683 650_2 $$2MeSH$$aPressure
000088683 650_2 $$2MeSH$$aSalts: chemistry
000088683 650_2 $$2MeSH$$aTemperature
000088683 650_2 $$2MeSH$$aZinc Oxide: chemistry
000088683 650_7 $$00$$2NLM Chemicals$$aSalts
000088683 650_7 $$01314-13-2$$2NLM Chemicals$$aZinc Oxide
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000088683 7001_ $$aKurakevych, O. O.
000088683 7001_ $$aSokolov, P. S.
000088683 7001_ $$aBaranov, A. N.
000088683 773__ $$0PERI:(DE-600)2006031-2$$a10.1021/jp201544f$$gVol. 115, p. 4354-4358$$p4354-4358$$q115<4354-4358$$tThe @journal of physical chemistry <Washington, DC> / A$$v115$$x1089-5639$$y2011
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000088683 9141_ $$a(c) American Chemical Society. No copyright permission for full text.$$y2011
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