%0 Journal Article
%A Kavetskyy, T.
%A Shpotyuk, O.
%A Kaban, I.
%A Hoyer, W.
%A Filipecki, J.
%A Iovu, M.
%A DESY
%T Structural study of As<sub>2</sub>S<sub>3</sub>0.6 (GeS<sub>2</sub>)0.4 glass
%J Journal of non-crystalline solids
%V 355
%@ 0022-3093
%C Amsterdam [u.a.]
%I Elsevier Science
%M PHPPUBDB-10133
%P 1801-1806
%D 2009
%Z © Elsevier B.V. ; Post referee fulltext in progress 2; Embargo 12 months from publication
%X As<sub>2</sub>S<sub>3</sub>)0.6(GeS<sub>2</sub>)0.4 glass in non-irradiated and γ-irradiated states has been studied by using high-energy synchrotron X-ray diffraction, extended X-ray absorption fine structure spectroscopy, and positron annihilation lifetime spectroscopy. The experimental results are explained by the local changes around As and Ge atoms upon irradiation. These changes are suggested to involve chemical bonds distortion, formation of defective bonds with wrong coordination, rotation of structural units and appearance of additional free volume in the glass network.
%F PUB:(DE-HGF)16
%9 Journal Article
%U <Go to ISI:>//WOS:000270620900006
%R 10.1016/j.jnoncrysol.2008.12.024
%U https://bib-pubdb1.desy.de/record/88137