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000087836 1001_ $$aLeita, L.
000087836 1101_ $$aDESY$$bExperiments with synchrotron radiation
000087836 245__ $$aSoil humic acids may favour the persistence of hexavalent chromium in soil
000087836 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2009
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000087836 440_0 $$0PERI:(DE-600)2013037-5$$aEnviron. Pollut.$$v157$$x0269-7491
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000087836 520__ $$aThe interaction between hexavalent chromium Cr(VI), as K(2)CrO(4), and standard humic acids (HAs) in bulk solution was studied using three complementary analytical methods: UV-Visible spectroscopy, X-ray absorption spectroscopy and differential pulse stripping voltammetry. The observed UV-Vis and X-ray absorption spectra showed that, under our experimental conditions, HAs did not induce reduction of Cr(VI) to its trivalent chemical form. The interaction between Cr(VI) and HAs has rather led to the formation of Cr(VI)-HAs micelles via supramolecular chemical processes. The reported results could contribute towards explaining the relative persistence of ecotoxic hexavalent chromium in soils.
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000087836 650_7 $$018540-29-9$$2NLM Chemicals$$achromium hexavalent ion
000087836 650_7 $$07440-47-3$$2NLM Chemicals$$aChromium
000087836 650_2 $$2MeSH$$aAbsorptiometry, Photon: methods
000087836 650_2 $$2MeSH$$aChromium: analysis
000087836 650_2 $$2MeSH$$aChromium: chemistry
000087836 650_2 $$2MeSH$$aEcotoxicology: methods
000087836 650_2 $$2MeSH$$aElectrochemistry: methods
000087836 650_2 $$2MeSH$$aHumic Substances
000087836 650_2 $$2MeSH$$aHydrogen-Ion Concentration
000087836 650_2 $$2MeSH$$aSoil: analysis
000087836 650_2 $$2MeSH$$aSoil Pollutants: analysis
000087836 650_2 $$2MeSH$$aSoil Pollutants: chemistry
000087836 650_2 $$2MeSH$$aSpectrophotometry, Ultraviolet: methods
000087836 650_2 $$2MeSH$$aTime Factors
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000087836 7001_ $$aMargon, A.
000087836 7001_ $$aPastrello, A.
000087836 7001_ $$aArcon, I.
000087836 7001_ $$aContin, M.
000087836 7001_ $$aMosetti, D.
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