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@ARTICLE{Wellenreuther:87625,
author = {Wellenreuther, G. and Parthasarathy, V. and Meyer-Klaucke,
W. and DESY},
title = {{T}owards a black-box for biological {EXAFS} data analysis.
{II}. {A}utomatic {B}io{XAS} {R}efinement and {A}nalysis
({ABRA})},
journal = {Journal of synchrotron radiation},
volume = {17},
issn = {0909-0495},
address = {Chester},
publisher = {IUCr},
reportid = {PHPPUBDB-10568},
pages = {25-35},
year = {2010},
abstract = {In biological systems, X-ray absorption spectroscopy (XAS)
can determine structural details of metal binding sites with
high resolution. Here a method enabling an automated
analysis of the corresponding EXAFS data is presented,
utilizing in addition to least-squares refinement the prior
knowledge about structural details and important fit
parameters. A metal binding motif is characterized by the
type of donor atoms and their bond lengths. These fit
results are compared by bond valance sum analysis and target
distances with established structures of metal binding
sites. Other parameters such as the Debye-Waller factor and
shift of the Fermi energy provide further insights into the
quality of a fit. The introduction of mathematical criteria,
their combination and calibration allows an automated
analysis of XAS data as demonstrated for a number of
examples. This presents a starting point for future
applications to all kinds of systems studied by XAS and
allows the algorithm to be transferred to data analysis in
other fields.},
keywords = {Algorithms / Binding Sites / Biopolymers: chemistry /
Metalloproteins: chemistry / Metals: chemistry / Protein
Binding / X-Ray Absorption Spectroscopy: methods /
Biopolymers (NLM Chemicals) / Metalloproteins (NLM
Chemicals) / Metals (NLM Chemicals)},
cin = {HASYLAB / EMBL},
ddc = {540},
cid = {$I:(DE-H253)HASYLAB_-2012_-20130307$ /
$I:(DE-H253)EMBL_-2012_-20130307$},
pnm = {FS In-house research / theory (POF1-550)},
pid = {G:(DE-H253)POF1-(In-house)-20130405},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:20029108},
UT = {WOS:000272990700003},
doi = {10.1107/S0909049509040576},
url = {https://bib-pubdb1.desy.de/record/87625},
}