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@ARTICLE{Matrai:85680,
author = {Matrai, J. and Lammens, W. and Jonckheer, A. and Le Roy, K.
and Rabijns, A. and Van den Ende, W. and De Maeyer, M. and
DESY},
title = {{A}n alternate sucrose binding mode in the {E}203{Q}
{A}rabidopsis invertase mutant: {A}n {X}-ray crystallography
and docking study},
journal = {Proteins},
volume = {71},
issn = {0887-3585},
address = {New York, NY},
publisher = {Wiley-Liss},
reportid = {PHPPUBDB-8387},
pages = {552-564},
year = {2008},
abstract = {In the present study, we report on the X-ray
crystallographic structure of a GH32 invertase mutant,
(i.e., the Arabidopsis thaliana cell-wall invertase 1-E203Q,
AtcwINV1-mutant) in complex with sucrose. This structure was
solved to reveal the features of sugar binding in the
catalytic pocket. However, as demonstrated by the X-ray
structure the sugar binding and the catalytic pocket
arrangement is significantly altered as compared with what
was expected based on previous X-ray structures on GH-J clan
enzymes. We performed a series of docking and molecular
dynamics simulations on various derivatives of AtcwINV1 to
reveal the reasons behind this modified sugar binding. Our
results demonstrate that the E203Q mutation introduced into
the catalytic pocket triggers conformational changes that
alter the wild type substrate binding. In addition, this
study also reveals the putative productive sucrose binding
modus in the wild type enzyme.},
keywords = {Amino Acid Substitution / Arabidopsis: enzymology /
Computer Simulation / Crystallization / Crystallography,
X-Ray / Models, Molecular / Protein Conformation: drug
effects / Sucrose: metabolism / beta-Fructofuranosidase:
chemistry / beta-Fructofuranosidase: genetics /
beta-Fructofuranosidase: metabolism / Sucrose (NLM
Chemicals) / beta-Fructofuranosidase (NLM Chemicals)},
cin = {EMBL},
ddc = {540},
cid = {$I:(DE-H253)EMBL_-2012_-20130307$},
pnm = {FS Beamline without reference (POF1-550)},
pid = {G:(DE-H253)POF1-No-Ref-20130405},
experiment = {EXP:(DE-H253)Unknown-BL-20150101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:17963237},
UT = {WOS:000254263400005},
doi = {10.1002/prot.21700},
url = {https://bib-pubdb1.desy.de/record/85680},
}