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@ARTICLE{Trinter:646074,
      author       = {Trinter, Florian and Hofierka, Jaroslav and Rist, Jonas and
                      Kircher, Max and Weller, Miriam and Melzer, Niklas and
                      Tsitsonis, Dimitrios and Geyer, Angelina and Kruse, Jan and
                      Kastirke, Gregor and Williams, Joshua and Miteva, Tsveta and
                      Doerner, Reinhard and Schoeffler, Markus and Kunitski,
                      Maksim and SISOURAT, Nicolas and Cederbaum, Lorenz and
                      Jahnke, Till},
      title        = {{T}racking the {C}omplex {D}ynamics of
                      {E}lectron-{T}ransfer-{M}ediated {D}ecay in {R}eal {S}pace
                      and {T}ime},
      journal      = {Journal of the American Chemical Society},
      volume       = {148},
      number       = {4},
      issn         = {0002-7863},
      address      = {Washington, DC},
      publisher    = {ACS Publications},
      reportid     = {PUBDB-2026-00714},
      pages        = {4126 - 4135},
      year         = {2026},
      note         = {Open Access},
      abstract     = {When an electronically excited atom or molecule is embedded
                      in a chemical environment as, e.g., in a liquid or a loosely
                      bound cluster, it can de-excite through mechanisms where
                      neighboring atoms or molecules are actively participating in
                      the decay: either by donating or accepting energy or
                      electrons. For such nonlocal decay channels, nuclear
                      dynamics play a crucial role as they have a direct impact on
                      the decay efficiency itself. Here, we present a detailed
                      study of the electron-transfer-mediated decay in a loosely
                      bound triatomic prototype system, combining experimental
                      results from a 5-fold coincidence measurement and
                      theoretical modeling of the decay process. Depending on the
                      decay time, we find that certain classes of molecular
                      geometries are favored for this type of decay. Our findings
                      provide an intuitive picture of how
                      electron-transfer-mediated decay proceeds. In particular,
                      our results confirm a roaming-like behavior of the atoms of
                      the trimer prior to its decay. Our combined theoretical and
                      experimental approach enables a comprehensive tracing of the
                      real-space properties of the decaying system in the time
                      domain.},
      cin          = {DOOR ; HAS-User},
      ddc          = {540},
      cid          = {I:(DE-H253)HAS-User-20120731},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20191330
                      EC (I-20191330-EC) / DFG project G:(GEPRIS)509471550 -
                      Dynamik photoionisations-induzierter Prozesse in
                      laser-präparierten Molekülen in der Gasphase und der
                      wässrigen Phase (509471550) / $ETMD_ICEC$ - Efficient
                      pathways to neutralization and radical production enabled by
                      environment (692657)},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20191330-EC /
                      G:(GEPRIS)509471550 / G:(EU-Grant)692657},
      experiment   = {EXP:(DE-H253)P-P04-20150101},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1021/jacs.5c15510},
      url          = {https://bib-pubdb1.desy.de/record/646074},
}