%0 Journal Article
%A Schmidt, Moritz
%A Hürtgen, Niklas H. H.
%A Virovets, Alexandr
%A Lerner, Hans-Wolfram
%A Wagner, Matthias
%T Complete Series of 1,2‐Bis(trihalogenosilyl)benzenes (F, Cl, Br, I): A Platform for Cooperating Lewis‐Acidic Sites in Close Quarters
%J Zeitschrift für anorganische und allgemeine Chemie
%V 652
%N 2
%@ 0044-2313
%C Weinheim
%I Wiley-VCH
%M PUBDB-2026-00670
%P e202500154
%D 2026
%X 1,2-Bis(trihalogenosilyl)benzenes are versatile synthetic building blocks and represent a unique class of ditopic Lewis acids. Building on the recently reported compound 1,2-(Cl3Si)2C6H2Me2 (1Cl; Me groups in 4,5-positions), the practical synthetic access to its sixfold fluorinated (1F), brominated (1Br), and iodinated (1I) congeners is disclosed. Compound 1F is obtained via Cl/F exchange on 1Cl using SbF3 (71
%F PUB:(DE-HGF)16
%9 Journal Article
%R 10.1002/zaac.202500154
%U https://bib-pubdb1.desy.de/record/645892