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@ARTICLE{Paulus:645886,
      author       = {Paulus, Daniel and Linz, Mario and Hansen, Anna-Lena and
                      van Smaalen, Sander and Moos, Ralf and Ulrich, Anke Silvia
                      and Schoenauer-Kamin, Daniela},
      title        = {{S}tructure matters: {A} synchrotron study reveals how
                      crystallite structure influences the deposition mechanism
                      for the powder aerosol deposition method},
      journal      = {Journal of the European Ceramic Society},
      volume       = {46},
      number       = {7},
      issn         = {0955-2219},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {PUBDB-2026-00666},
      pages        = {118127},
      year         = {2026},
      abstract     = {Powder aerosol deposition (PAD or ADM) is a coating
                      technique to produce ceramic films at room temperature.
                      Although the deposition mechanism has been clarified in some
                      respects, unanswered questions remain. The present work
                      reports films of titanium oxide, which forms a typical PAD
                      microstructure, and films of incommensurate misfit-layered
                      calcium cobalt oxide (Ca$_3$Co$_4$O$_{9-δ}$, CCO-349),
                      which forms a atypical film. For this work, films made of
                      these two materials were examined using X-ray diffraction
                      with synchrotron radiation and a scanning electron
                      microscopy. It turned out that due to its aperiodic crystal
                      structure, CCO-349 can be deformed more easily than
                      conventional technical ceramics like TiO$_2$. The
                      deformation occurs when the layers in the crystal slide in
                      the direction of the misfit. As a result, it is unnecessary
                      to break the crystals, and a larger crystallite size remains
                      in the film. Therefore, PAD films of CCO-349 have a
                      different microstructure.},
      cin          = {FS DOOR-User},
      ddc          = {660},
      cid          = {$I:(DE-H253)FS_DOOR-User-20241023$},
      pnm          = {6G3 - PETRA III (DESY) (POF4-6G3) / FS-Proposal: I-20230953
                      (I-20230953) / FS-Proposal: I-20240866 (I-20240866) / DFG
                      project G:(GEPRIS)544448150 - PAD-Flex-TEG: Direkt aus dem
                      Pulver kaltabgeschiedene nanokristalline µm-dicke
                      Bismuttellurid-Schichten für flexible thermoelektrische
                      Generatoren (544448150) / FestBatt-Oxide - Materialplattform
                      'Oxide' im Rahmen des Kompetenzclusters für
                      Festkörperbatterien (13XP0173A)},
      pid          = {G:(DE-HGF)POF4-6G3 / G:(DE-H253)I-20230953 /
                      G:(DE-H253)I-20240866 / G:(GEPRIS)544448150 /
                      G:(BMBF)13XP0173A},
      experiment   = {EXP:(DE-H253)P-P02.1-20150101},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1016/j.jeurceramsoc.2026.118127},
      url          = {https://bib-pubdb1.desy.de/record/645886},
}