000643437 001__ 643437
000643437 005__ 20260113122604.0
000643437 0247_ $$2doi$$a10.1021/jacs.5c05172
000643437 0247_ $$2ISSN$$a0002-7863
000643437 0247_ $$2ISSN$$a1520-5126
000643437 0247_ $$2ISSN$$a1943-2984
000643437 037__ $$aPUBDB-2026-00198
000643437 041__ $$aEnglish
000643437 082__ $$a540
000643437 1001_ $$0P:(DE-H253)PIP1103159$$aLiu, Shangpu$$b0$$eCorresponding author
000643437 245__ $$aOrientation-Driven Chirality Funnels in Chiral Low-Dimensional Lead-Halide Perovskite Heterostructures
000643437 260__ $$aWashington, DC$$bACS Publications$$c2025
000643437 3367_ $$2DRIVER$$aarticle
000643437 3367_ $$2DataCite$$aOutput Types/Journal article
000643437 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1768230525_2487195
000643437 3367_ $$2BibTeX$$aARTICLE
000643437 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000643437 3367_ $$00$$2EndNote$$aJournal Article
000643437 500__ $$aWaiting for fulltext 
000643437 520__ $$aChiral hybrid metal-halide perovskites show low-symmetry crystal structures, large Rashba splitting, spin-filtering, and strong chiroptical activity. Circular dichroism and circularly polarized photoluminescence have been investigated in chiral perovskites with increasingly distorted chiral structures. Here, we report the fabrication of chiral (R/S)-EBAPbI3 (EBA = α-ethylbenzylamine) single crystals, which possess highly distorted octahedral structures with a high angle variance value of ∼68 degree2. Using control in the fabrication conditions, we transfer chiral single crystals to thin films and achieve different crystal orientation preferences that induce tunable chiroptical properties to their heterostructures with PbI2 nanodomains, which we characterize with in situ X-ray diffraction and grazing-incidence wide-angle X-ray scattering measurements. Using transient chiroptical spectroscopies, we resolve photoexcited charge carrier dynamics and chirality transfer processes in such heterostructures down to cryogenic temperatures. We observe rapid carrier transfer along the in-plane (002) facets in chiral perovskite phases to PbI2 nanostructures within the initial few picoseconds, while carrier transfer along the out-of-plane (002) facets occurs at a slower rate. This fast transfer process leads to high photoluminescence intensities and large degrees of circular polarization in the emission from PbI2 nanodomains at cryogenic temperatures. Our findings report a multidimensional chiral-achiral heterostructure which takes advantage of controllable chirality transfer and offers new routes for future spintronic and chiroptical applications. 
000643437 536__ $$0G:(DE-HGF)POF4-6G3$$a6G3 - PETRA III (DESY) (POF4-6G3)$$cPOF4-6G3$$fPOF IV$$x0
000643437 536__ $$0G:(DE-H253)I-20230055$$aFS-Proposal: I-20230055 (I-20230055)$$cI-20230055$$x1
000643437 536__ $$0G:(GEPRIS)390776260$$aDFG project G:(GEPRIS)390776260 - EXC 2089: e-conversion (390776260)$$c390776260$$x2
000643437 588__ $$aDataset connected to CrossRef, Journals: bib-pubdb1.desy.de
000643437 693__ $$0EXP:(DE-H253)P-P03-20150101$$1EXP:(DE-H253)PETRAIII-20150101$$6EXP:(DE-H253)P-P03-20150101$$aPETRA III$$fPETRA Beamline P03$$x0
000643437 7001_ $$aZerhoch, Jonathan$$b1
000643437 7001_ $$aHeindl, Markus W.$$b2
000643437 7001_ $$aZhang, Chaoran$$b3
000643437 7001_ $$00000-0002-8792-9669$$aKodalle, Tim$$b4
000643437 7001_ $$aSun, Kun$$b5
000643437 7001_ $$aShcherbakov, Andrii$$b6
000643437 7001_ $$0P:(DE-H253)PIP1099730$$aBodnar, Stanislav$$b7
000643437 7001_ $$aMiah, Milon$$b8
000643437 7001_ $$aGholipoor, Mohammad$$b9
000643437 7001_ $$aJandl, Christian$$b10
000643437 7001_ $$00000-0003-4663-3949$$aPöthig, Alexander$$b11
000643437 7001_ $$00000-0001-6431-4197$$aBallmann, Joachim$$b12
000643437 7001_ $$aSharp, Ian D.$$b13
000643437 7001_ $$0P:(DE-H253)PIP1007825$$aMüller-Buschbaum, Peter$$b14
000643437 7001_ $$aSutter-Fella, Carolin M.$$b15
000643437 7001_ $$00000-0002-1557-8361$$aPaetzold, Ulrich W.$$b16
000643437 7001_ $$0P:(DE-H253)PIP1081472$$aDeschler, Felix$$b17$$eCorresponding author
000643437 773__ $$0PERI:(DE-600)1472210-0$$a10.1021/jacs.5c05172$$gVol. 147, no. 19, p. 16681 - 16693$$n19$$p16681 - 16693$$tJournal of the American Chemical Society$$v147$$x0002-7863$$y2025
000643437 8564_ $$uhttps://bib-pubdb1.desy.de/record/643437/files/orientation-driven-chirality-funnels-in-chiral-low-dimensional-lead-halide-perovskite-heterostructures.pdf$$yRestricted
000643437 8564_ $$uhttps://bib-pubdb1.desy.de/record/643437/files/orientation-driven-chirality-funnels-in-chiral-low-dimensional-lead-halide-perovskite-heterostructures.pdf?subformat=pdfa$$xpdfa$$yRestricted
000643437 909CO $$ooai:bib-pubdb1.desy.de:643437$$pVDB
000643437 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1103159$$aExternal Institute$$b0$$kExtern
000643437 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1103159$$aEuropean XFEL$$b0$$kXFEL.EU
000643437 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1099730$$aExternal Institute$$b7$$kExtern
000643437 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1099730$$aEuropean XFEL$$b7$$kXFEL.EU
000643437 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1007825$$aExternal Institute$$b14$$kExtern
000643437 9101_ $$0I:(DE-588)1043621512$$6P:(DE-H253)PIP1081472$$aEuropean XFEL$$b17$$kXFEL.EU
000643437 9101_ $$0I:(DE-HGF)0$$6P:(DE-H253)PIP1081472$$aExternal Institute$$b17$$kExtern
000643437 9131_ $$0G:(DE-HGF)POF4-6G3$$1G:(DE-HGF)POF4-6G0$$2G:(DE-HGF)POF4-600$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$aDE-HGF$$bForschungsbereich Materie$$lGroßgeräte: Materie$$vPETRA III (DESY)$$x0
000643437 9141_ $$y2025
000643437 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz$$d2024-12-13$$wger
000643437 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bJ AM CHEM SOC : 2022$$d2024-12-13
000643437 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2024-12-13
000643437 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2024-12-13
000643437 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2024-12-13
000643437 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2024-12-13
000643437 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2024-12-13
000643437 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2024-12-13
000643437 915__ $$0StatID:(DE-HGF)1050$$2StatID$$aDBCoverage$$bBIOSIS Previews$$d2024-12-13
000643437 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2024-12-13
000643437 915__ $$0StatID:(DE-HGF)1030$$2StatID$$aDBCoverage$$bCurrent Contents - Life Sciences$$d2024-12-13
000643437 915__ $$0StatID:(DE-HGF)1200$$2StatID$$aDBCoverage$$bChemical Reactions$$d2024-12-13
000643437 915__ $$0StatID:(DE-HGF)1190$$2StatID$$aDBCoverage$$bBiological Abstracts$$d2024-12-13
000643437 915__ $$0StatID:(DE-HGF)1210$$2StatID$$aDBCoverage$$bIndex Chemicus$$d2024-12-13
000643437 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2024-12-13
000643437 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2024-12-13
000643437 915__ $$0StatID:(DE-HGF)9915$$2StatID$$aIF >= 15$$bJ AM CHEM SOC : 2022$$d2024-12-13
000643437 9201_ $$0I:(DE-H253)HAS-User-20120731$$kDOOR ; HAS-User$$lDOOR-User$$x0
000643437 980__ $$ajournal
000643437 980__ $$aVDB
000643437 980__ $$aI:(DE-H253)HAS-User-20120731
000643437 980__ $$aUNRESTRICTED