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@ARTICLE{Walmsley:642750,
author = {Walmsley, Tiffany and Allum, Felix and Harries, James and
Kumagai, Yoshiaki and McManus, Joseph and Nagaya, Kiyonobu
and Britton, Mathew and Brouard, Mark and Bucksbaum, Philip
and Fushitani, Mizuho and Gabalski, Ian and Gejo, Tatsuo and
Hockett, Paul and Howard, Andrew and Iwayama, Hiroshi and
Kukk, Edwin and Lam, Chow-shing and Minns, Russell and
Niozu, Akinobu and Nishimuro, Sekito and Niskanen, Johannes
and Owada, Shigeki and Razmus, Weronika and Rolles, Daniel
and Somper, James and Ueda, Kiyoshi and Unwin, James and
Wada, Shin-ichi and Woodhouse, Joanne and Forbes, Ruaridh
and Burt, Michael and Warne, Emily},
title = {{T}he inner-shell ionization and fragmentation of
selenophene at 120 e{V}},
reportid = {PUBDB-2025-05599},
year = {2025},
abstract = {Three-dimensional velocity-map imaging and covariance
analysis were used to identify over 50 fragmentation
channels produced following the inner-shell ionization of
selenophene at 120 eV. The majority resulted in two or three
'heavy' products containing selenium or carbon, many of
which had identical mass-to-charge ratios but different
chemical compositions due to the degree of hydrogenation and
the selenium isotope involved. Covariance analysis was used
to isolate these reaction channels and to provide estimates
of their relative yields. In combination with prior similar
studies on thiophene and furan, the current results indicate
that the nature of the heteroatom significantly influences
the charge redistribution and bond cleavage dynamics induced
by the Auger-Meitner process, and demonstrate the
sensitivity of inner-shell ionization dynamics to the
molecular and electronic structures of heterocyclic
systems.},
cin = {FS-FLASH},
cid = {I:(DE-H253)FS-FLASH-20140814},
pnm = {631 - Matter – Dynamics, Mechanisms and Control
(POF4-631)},
pid = {G:(DE-HGF)POF4-631},
experiment = {EXP:(DE-MLZ)External-20140101},
typ = {PUB:(DE-HGF)25},
doi = {10.21203/rs.3.rs-7925497/v1},
url = {https://bib-pubdb1.desy.de/record/642750},
}