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000642750 0247_ $$2doi$$a10.21203/rs.3.rs-7925497/v1
000642750 037__ $$aPUBDB-2025-05599
000642750 041__ $$aEnglish
000642750 1001_ $$aWalmsley, Tiffany$$b0
000642750 245__ $$aThe inner-shell ionization and fragmentation of selenophene at 120 eV
000642750 260__ $$c2025
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000642750 520__ $$aThree-dimensional velocity-map imaging and covariance analysis were used to identify over 50 fragmentation channels produced following the inner-shell ionization of selenophene at 120 eV. The majority resulted in two or three 'heavy' products containing selenium or carbon, many of which had identical mass-to-charge ratios but different chemical compositions due to the degree of hydrogenation and the selenium isotope involved. Covariance analysis was used to isolate these reaction channels and to provide estimates of their relative yields. In combination with prior similar studies on thiophene and furan, the current results indicate that the nature of the heteroatom significantly influences the charge redistribution and bond cleavage dynamics induced by the Auger-Meitner process, and demonstrate the sensitivity of inner-shell ionization dynamics to the molecular and electronic structures of heterocyclic systems.
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000642750 7001_ $$0P:(DE-H253)PIP1032123$$aAllum, Felix$$b1
000642750 7001_ $$aHarries, James$$b2
000642750 7001_ $$aKumagai, Yoshiaki$$b3
000642750 7001_ $$aMcManus, Joseph$$b4
000642750 7001_ $$aNagaya, Kiyonobu$$b5
000642750 7001_ $$aBritton, Mathew$$b6
000642750 7001_ $$aBrouard, Mark$$b7
000642750 7001_ $$aBucksbaum, Philip$$b8
000642750 7001_ $$aFushitani, Mizuho$$b9
000642750 7001_ $$aGabalski, Ian$$b10
000642750 7001_ $$aGejo, Tatsuo$$b11
000642750 7001_ $$aHockett, Paul$$b12
000642750 7001_ $$aHoward, Andrew$$b13
000642750 7001_ $$aIwayama, Hiroshi$$b14
000642750 7001_ $$aKukk, Edwin$$b15
000642750 7001_ $$aLam, Chow-shing$$b16
000642750 7001_ $$aMinns, Russell$$b17
000642750 7001_ $$aNiozu, Akinobu$$b18
000642750 7001_ $$aNishimuro, Sekito$$b19
000642750 7001_ $$aNiskanen, Johannes$$b20
000642750 7001_ $$aOwada, Shigeki$$b21
000642750 7001_ $$aRazmus, Weronika$$b22
000642750 7001_ $$aRolles, Daniel$$b23
000642750 7001_ $$aSomper, James$$b24
000642750 7001_ $$aUeda, Kiyoshi$$b25
000642750 7001_ $$aUnwin, James$$b26
000642750 7001_ $$aWada, Shin-ichi$$b27
000642750 7001_ $$aWoodhouse, Joanne$$b28
000642750 7001_ $$aForbes, Ruaridh$$b29
000642750 7001_ $$aBurt, Michael$$b30
000642750 7001_ $$aWarne, Emily$$b31
000642750 773__ $$a10.21203/rs.3.rs-7925497/v1
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000642750 9141_ $$y2025
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