TY  - EJOUR
AU  - Dovgaliuk, Iurii
AU  - Chen, Bingbing
AU  - Melillo, Arianna
AU  - Wahiduzzaman, Mohammad
AU  - Khadiev, Azat
AU  - Novikov, Dmitri
AU  - Achenbach, Bastian
AU  - Ruser, Niklas
AU  - Gosch, Jonas
AU  - Stock, Norbert
AU  - Maurin, Guillaume
AU  - Mouchaham, Georges
AU  - Serre, Christian
TI  - In-situ Diffraction Crystallization Study of a porous Ti(IV) oxo-cluster carboxylate MOF and its Water-Induced Ti(III) Formate
M1  - PUBDB-2025-05595
PY  - 2025
AB  - The in-situ crystallization kinetics of the highly porous Ti(IV)12 oxo-cluster based metal-organic framework (MOF) MIP-177(Ti)-LT (MIP: Materials from Institute of porous solids of Paris, LT: Low Temperature) were studied by synchrotron time-resolved powder X-ray diffraction. When dry formic acid (FA) was used as solvent the crystallization does follow the Johnson-Mehl-Avrami-Kolmogorov kinetics with an energy barrier of 74 kJ·mol-1 without any observed intermediate crystalline phases. However, when small quantities of water (≥ 2.5 vol
LB  - PUB:(DE-HGF)25
DO  - DOI:10.26434/chemrxiv-2025-dl8vn-v2
UR  - https://bib-pubdb1.desy.de/record/642746
ER  -