%0 Electronic Article
%A Dovgaliuk, Iurii
%A Chen, Bingbing
%A Melillo, Arianna
%A Wahiduzzaman, Mohammad
%A Khadiev, Azat
%A Novikov, Dmitri
%A Achenbach, Bastian
%A Ruser, Niklas
%A Gosch, Jonas
%A Stock, Norbert
%A Maurin, Guillaume
%A Mouchaham, Georges
%A Serre, Christian
%T In-situ Diffraction Crystallization Study of a porous Ti(IV) oxo-cluster carboxylate MOF and its Water-Induced Ti(III) Formate
%M PUBDB-2025-05595
%D 2025
%X The in-situ crystallization kinetics of the highly porous Ti(IV)12 oxo-cluster based metal-organic framework (MOF) MIP-177(Ti)-LT (MIP: Materials from Institute of porous solids of Paris, LT: Low Temperature) were studied by synchrotron time-resolved powder X-ray diffraction. When dry formic acid (FA) was used as solvent the crystallization does follow the Johnson-Mehl-Avrami-Kolmogorov kinetics with an energy barrier of 74 kJ·mol-1 without any observed intermediate crystalline phases. However, when small quantities of water (≥ 2.5 vol
%F PUB:(DE-HGF)25
%9 Preprint
%R 10.26434/chemrxiv-2025-dl8vn-v2
%U https://bib-pubdb1.desy.de/record/642746