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@ARTICLE{Wang:641822,
author = {Wang, Ao and Pethö, László and Hegedűs, Zoltán and
Wątroba, Maria and Michler, Johann and Veselý, Jozef and
Minárik, Peter and Nagy, Péter and Gubicza, Jeno},
title = {{H}igh-entropy alloy mapping in the
{C}o-{C}r-{F}e-{M}o-{N}i-{W} compositional library using a
combinatorial thin film},
journal = {Journal of alloys and compounds},
volume = {1048},
issn = {0925-8388},
address = {Lausanne},
publisher = {Elsevier},
reportid = {PUBDB-2025-05204},
pages = {185264},
year = {2025},
abstract = {Experiments were conducted to study the structure and
mechanical behavior of high-entropy alloys (HEAs) in the
Co-Cr-Fe-Mo-Ni-W compositional library. This investigation
was performed on a 3 μm thick combinatorial thin film
deposited on a single crystal silicon (c-Si) substrate by
magnetron sputtering technique. The chemical composition for
each element varied in the range of about $5–40 at\%.$
The mapping of the structure was carried out by synchrotron
X-ray diffraction while the mechanical behavior was studied
by nanoindentation. A complementary transmission electron
microscopy investigation at some selected compositions was
also performed. Most of the studied compositions formed an
amorphous structure while nanocrystalline body-centered
cubic (bcc) and hexagonal close-packed (hcp) phases were
detected in the vicinity of W/Mo and Co/Ni elemental
sources, respectively. The hcp structure contained a very
high density of stacking faults on the basal planes. The
variation of the phase composition can be related to the
change of valence electron concentration. The lattice
constants in the crystalline regions of the combinatorial
sample changed in accordance with the variation of the
average atomic radius. The combinatorial sample contained
pores which significantly reduced the hardness. The highest
hardness values (7.8 ± 0.3 GPa) were detected in the
bcc region for the compositions of $8.1 \%$ Co –
$25.6 \%$ Cr – $6.9 \%$ Fe – $16.4 \%$ Mo –
$9.1 \%$ Ni – $33.9 \%$ W $(at\%).$},
cin = {DOOR ; HAS-User / FS-PETRA-D},
ddc = {540},
cid = {I:(DE-H253)HAS-User-20120731 /
I:(DE-H253)FS-PETRA-D-20210408},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3)},
pid = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3},
experiment = {EXP:(DE-H253)P-P21.2-20150101},
typ = {PUB:(DE-HGF)16},
doi = {10.1016/j.jallcom.2025.185264},
url = {https://bib-pubdb1.desy.de/record/641822},
}