% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Mollick:641738,
      author       = {Mollick, Samraj and Morgante, Carmelo and Christensen,
                      Anders K. R. and Finkler, Jonas A. and Youngman, Randall E.
                      and Nielsen, Anders B. and Lu, Ronghui and Sørensen, Søren
                      S. and Johansen, Morten and Karlsen, Martin Aaskov and
                      Stathopoulos, Vassilis N. and Lock, Nina and Nielsen, Niels
                      Chr. and Boffa, Vittorio and Smedskjaer, Morten M.},
      title        = {{S}elective mineral recovery from seawater by
                      ion-exchangeable metal-organic framework glasses},
      reportid     = {PUBDB-2025-05149},
      year         = {2025},
      note         = {We acknowledge the Deutsche Forschungsgemeinschaft (DFG)
                      (withinthe SPP 2196: grant numbers GR 5505/3-1, RI
                      1551/15-2, RI 1551/12-2,RI1551/22-1, OL 462/4-2, OL 462/7-1,
                      MA 2359/38-1 and HA 4382/16-1)and the Bundesministerium für
                      Bildung und Forschung (BMBF) (grantnumber 01DP20008) for
                      financial support.},
      abstract     = {The transition to clean energy and sustainable technologies
                      necessitates securing precious metals, yet traditional
                      land-based mining is increasingly unsustainable. Seawater
                      holds immense potential as a mineral source, but its
                      intricate ionic composition limits current extraction
                      techniques. Here, we report a family of ion-exchangeable
                      materials by grafting phosphate groups onto metal-organic
                      framework glasses, followed by precise heat and aqueous
                      treatments. This process introduces facile exchangeable ions
                      and exposes active functional groups. Based on these
                      structural features, the materials exhibit superior
                      performance in selective recovery of magnesium and lithium
                      from various natural seawater samples, surpassing a typical
                      commercial resin in uptake rate, capacity, and
                      recyclability. Our work presents a promising route for
                      designing efficient adsorbents to extract valuable minerals
                      from unconventional sources and help to secure the raw
                      materials vital for a low-carbon future.},
      cin          = {DOOR ; HAS-User / FS-PETRA-D},
      cid          = {I:(DE-H253)HAS-User-20120731 /
                      I:(DE-H253)FS-PETRA-D-20210408},
      pnm          = {632 - Materials – Quantum, Complex and Functional
                      Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
                      05K19VTA - Entwicklung einer kompakten Probenumgebung mit
                      Spin-Coater für in-situ Röntgenstreuung an PETRA III.
                      (BMBF-05K19VTA) / FOXES - Fully Oxide-based Zero-Emission
                      and Portable Energy Supply (951774) / TRIUMPH - Triple
                      junction solar modules based on perovskites and silicon for
                      high performance, low-cost and small environmental footprint
                      (101075725) / FS-Proposal: I-20211642 (I-20211642) /
                      FS-Proposal: II-20190761 (II-20190761) / FS-Proposal:
                      I-20221269 (I-20221269)},
      pid          = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
                      G:(DE-Ds200)BMBF-05K19VTA / G:(EU-Grant)951774 /
                      G:(EU-Grant)101075725 / G:(DE-H253)I-20211642 /
                      G:(DE-H253)II-20190761 / G:(DE-H253)I-20221269},
      experiment   = {EXP:(DE-H253)P-P08-20150101},
      typ          = {PUB:(DE-HGF)25},
      doi          = {10.26434/chemrxiv-2025-90l2h-v2},
      url          = {https://bib-pubdb1.desy.de/record/641738},
}