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000641738 005__ 20260209140047.0
000641738 0247_ $$2doi$$a10.26434/chemrxiv-2025-90l2h-v2
000641738 0247_ $$2datacite_doi$$a10.3204/PUBDB-2025-05149
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000641738 037__ $$aPUBDB-2025-05149
000641738 041__ $$aEnglish
000641738 1001_ $$aMollick, Samraj$$b0
000641738 245__ $$aSelective mineral recovery from seawater by ion-exchangeable metal-organic framework glasses
000641738 260__ $$c2025
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000641738 500__ $$aWe acknowledge the Deutsche Forschungsgemeinschaft (DFG) (withinthe SPP 2196: grant numbers GR 5505/3-1, RI 1551/15-2, RI 1551/12-2,RI1551/22-1, OL 462/4-2, OL 462/7-1, MA 2359/38-1 and HA 4382/16-1)and the Bundesministerium für Bildung und Forschung (BMBF) (grantnumber 01DP20008) for financial support.
000641738 520__ $$aThe transition to clean energy and sustainable technologies necessitates securing precious metals, yet traditional land-based mining is increasingly unsustainable. Seawater holds immense potential as a mineral source, but its intricate ionic composition limits current extraction techniques. Here, we report a family of ion-exchangeable materials by grafting phosphate groups onto metal-organic framework glasses, followed by precise heat and aqueous treatments. This process introduces facile exchangeable ions and exposes active functional groups. Based on these structural features, the materials exhibit superior performance in selective recovery of magnesium and lithium from various natural seawater samples, surpassing a typical commercial resin in uptake rate, capacity, and recyclability. Our work presents a promising route for designing efficient adsorbents to extract valuable minerals from unconventional sources and help to secure the raw materials vital for a low-carbon future.
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000641738 7001_ $$00000-0002-2825-522X$$aMorgante, Carmelo$$b1
000641738 7001_ $$aChristensen, Anders K. R.$$b2
000641738 7001_ $$aFinkler, Jonas A.$$b3
000641738 7001_ $$00000-0002-6647-9865$$aYoungman, Randall E.$$b4
000641738 7001_ $$aNielsen, Anders B.$$b5
000641738 7001_ $$aLu, Ronghui$$b6
000641738 7001_ $$aSørensen, Søren S.$$b7
000641738 7001_ $$aJohansen, Morten$$b8
000641738 7001_ $$0P:(DE-H253)PIP1089139$$aKarlsen, Martin Aaskov$$b9
000641738 7001_ $$aStathopoulos, Vassilis N.$$b10
000641738 7001_ $$aLock, Nina$$b11
000641738 7001_ $$00000-0003-2978-4366$$aNielsen, Niels Chr.$$b12
000641738 7001_ $$0P:(DE-HGF)0$$aBoffa, Vittorio$$b13$$eCorresponding author
000641738 7001_ $$0P:(DE-H253)PIP1031535$$aSmedskjaer, Morten M.$$b14$$eCorresponding author
000641738 773__ $$a10.26434/chemrxiv-2025-90l2h-v2
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