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@ARTICLE{Maschwitz:641735,
author = {Maschwitz, Timo and Merten, Lena and Ünlü, Feray and
Majewski, Martin and Haddadi Barzoki, Fatemeh and Wu, Zijin
and Öz, Seren Dilara and Kreusel, Cedric and Theisen,
Manuel and Wang, Pang and Schiffer, Maximilian and
Boccarella, Gianluca and Marioth, Gregor and Weidner, Henrik
and Schultheis, Sarah and Schieferstein, Tim and
Gidaszewski, Dawid and Julliev, Zavkiddin and Kneschaurek,
Ekaterina and Munteanu, Valentin and Zaluzhnyy, Ivan and
Bertram, Florian and Jaffrès, Anaël and He, Junjie and
Ashurov, Nigmat and Stolterfoht, Martin and Wolff, Christian
M. and Unger, Eva and Olthof, Selina and Brocks, Geert and
Tao, Shuxia and Grüninger, Helen and Ronsin, Olivier J. J.
and Harting, Jens and Kotthaus, Andreas F. and Kirsch,
Stefan F. and Mathur, Sanjay and Hinderhofer, Alexander and
Schreiber, Frank and Riedl, Thomas and Brinkmann, Kai
Oliver},
title = {{H}ow crystallization additives govern halide perovskite
grain growth},
journal = {Nature Communications},
volume = {16},
number = {1},
issn = {2041-1723},
address = {[London]},
publisher = {Springer Nature},
reportid = {PUBDB-2025-05146},
pages = {9894},
year = {2025},
note = {cc-byproject hinzufügen: 01DP20008},
abstract = {The preparation of perovskite solar cells from the liquid
phase is a cornerstone of their immense potential. However,
a clear relationship between the precursor ink and the
formation of the resulting perovskite is missing.
Established theories, such as heterogeneous nucleation and
lead complex colloid formation, often prove unreliable,
which has led to an overreliance on heuristics. Most
high-performing perovskites use additives to control
crystallization. Their role during crystallization is,
however, elusive. Here, we provide evidence that typical
crystallization additives do not predominantly impact the
nucleation phase but rather facilitate coarsening grain
growth by increasing ion mobility across grain boundaries.
Drawing from the insights of our broad, interdisciplinary
study that combines ex and in situ characterization methods,
devices, simulations, and density function theory
calculation, we propose a concept that proves valid for
various additives and perovskite formulations. Moreover, we
establish a direct link between additive engineering and
perovskite post-processing, offering a unified framework for
advancing material design and process engineering.},
cin = {DOOR ; HAS-User / FS-PETRA-D},
ddc = {500},
cid = {I:(DE-H253)HAS-User-20120731 /
I:(DE-H253)FS-PETRA-D-20210408},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / 6G3 - PETRA III (DESY) (POF4-6G3) /
05K19VTA - Entwicklung einer kompakten Probenumgebung mit
Spin-Coater für in-situ Röntgenstreuung an PETRA III.
(BMBF-05K19VTA) / FOXES - Fully Oxide-based Zero-Emission
and Portable Energy Supply (951774) / FS-Proposal:
II-20190761 (II-20190761) / FS-Proposal: I-20221269
(I-20221269) / FS-Proposal: I-20211642 (I-20211642)},
pid = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G3 /
G:(DE-Ds200)BMBF-05K19VTA / G:(EU-Grant)951774 /
G:(DE-H253)II-20190761 / G:(DE-H253)I-20221269 /
G:(DE-H253)I-20211642},
experiment = {EXP:(DE-H253)P-P08-20150101},
typ = {PUB:(DE-HGF)16},
doi = {10.1038/s41467-025-65484-7},
url = {https://bib-pubdb1.desy.de/record/641735},
}