TY  - JOUR
AU  - Velazquez-Garcia, Jose de Jesus
AU  - Bintas, Christos
AU  - Khademhir, Faegheh
AU  - Knjo, Bassima
AU  - Ekineken, Aliyenur
AU  - Hain, Fabienne
AU  - Techert, Simone
TI  - Crystal structure of tris[hexakis(imidazole)cobalt(II)] bis(benzene-1,3,5-tricarboxylate)
JO  - Acta crystallographica / Section E
VL  - 81
IS  - 12
SN  - 2056-9890
CY  - Chester
PB  - International Union of Crystallography
M1  - PUBDB-2025-04783
SP  - 1186 - 1188
PY  - 2025
N1  - ISSN 2056-9890 not unique: **2 hits**.
AB  - The title compound, [CoII(C3N2H4)6]3·[C9H3O6]2 (1), was synthesised from cobalt chloride(II), benzene-1,3,5-tricarboxylic acid (H3btc) and imidazole (Im) in an ethanol/DMF mixture via slow evaporation at room temperature. The structure of 1 is here reported. This compound consists of three hexakis(imidazole)cobalt(II) cations and two trimesate anions. Examination of the crystal packing shows the formation of 1D column stacks of ions propagating along the c axis. The packing interactions are primarily driven by N—H···O hydrogen bonding between anions and cations.
LB  - PUB:(DE-HGF)16
DO  - DOI:10.1107/S2056989025010060
UR  - https://bib-pubdb1.desy.de/record/640461
ER  -