%0 Journal Article
%A Velazquez-Garcia, Jose de Jesus
%A Bintas, Christos
%A Khademhir, Faegheh
%A Knjo, Bassima
%A Ekineken, Aliyenur
%A Hain, Fabienne
%A Techert, Simone
%T Crystal structure of tris[hexakis(imidazole)cobalt(II)] bis(benzene-1,3,5-tricarboxylate)
%J Acta crystallographica / Section E
%V 81
%N 12
%@ 2056-9890
%C Chester
%I International Union of Crystallography
%M PUBDB-2025-04783
%P 1186 - 1188
%D 2025
%Z ISSN 2056-9890 not unique: **2 hits**.
%X The title compound, [CoII(C3N2H4)6]3·[C9H3O6]2 (1), was synthesised from cobalt chloride(II), benzene-1,3,5-tricarboxylic acid (H3btc) and imidazole (Im) in an ethanol/DMF mixture via slow evaporation at room temperature. The structure of 1 is here reported. This compound consists of three hexakis(imidazole)cobalt(II) cations and two trimesate anions. Examination of the crystal packing shows the formation of 1D column stacks of ions propagating along the c axis. The packing interactions are primarily driven by N—H···O hydrogen bonding between anions and cations.
%F PUB:(DE-HGF)16
%9 Journal Article
%R 10.1107/S2056989025010060
%U https://bib-pubdb1.desy.de/record/640461